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What is likage isomerism ? Explain with ...

What is likage isomerism ? Explain with an example.

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Two or more co-ordination compounds which have same molecular formula but differs in the modes of attachment of ambident ligand to the central metal ion.
Ex : `underset("Pentaamminenitrito-N-cobalt(III)chloride")([Co(NH_(3))_(5)(NO_(2))]Cl_(2))`
Ex : `underset("Pentaamminenitrito-O-cobalt(III) chloride")([Co(NH_(3))_(5)(ONO)]Cl_(2))`
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SUBHASH PUBLICATION-CO-ORDINATION COMPOUNDS-Questions
  1. Draw cis nd trans isomers of [Co(NH(3))(4)Cl(2)]^(+) ion.

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  2. Draw the structures of geometrical isomers of [Fe(NH(3))(2)(CN)(4)]^-.

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  3. Draw the structures of geometrical isomers of [CoCl(2)(en)(2)]^(+).

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  4. Give the facial (fac) and meridional (mer) isomeric structures of [Co(...

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  5. Draw the optical isomers of [CO(en)(3)]^(2+).

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  6. Draw the optical isomers of [Pt(Cl)(2)(en)(2)]^(2+).

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  7. Draw the optical isomers of [CrCl(2)("ox")(2)]^(2-).

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  8. Explain ionisation isomerisation with an example.

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  9. What is likage isomerism ? Explain with an example.

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  10. What is an ambidentate ligand ? Name the type of structural isomerism ...

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  11. Describe the structure and magnetic behaviour of [Ni(CN)4]^(2-) ion on...

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  12. Explain the hybridisation, geometry and magnetic property of [Ni(Cl)(4...

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  13. Explain the hybridisation, geometry and magnetic prpoperty of [Co(NH(3...

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  14. Explain the hybridisation, geometry and magnetic property of [CoF(6)]^...

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  15. [NiCl(4)]^(-2) and [Ni(CN)(4)]^(-2) resemble in

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  16. [Co(NH(3))(6)]^(3+) & [CoF(6)]^(3-) both are complexes of Co(III), but...

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  17. Which set of d-orbitals of metals ion or atom experience more repulsio...

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  18. When a linkage isomerism is possible for co-ordination compounds ?

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  19. Indicate the types of isomerism exhibited by the follow complexes and ...

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  20. According to crystal filed theory , five d-orbitals of an octahedral c...

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