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Explain the acidic nature of alcohols....

Explain the acidic nature of alcohols.

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Alcohols react with active metals such as sodium to yield corresponding alkoxides and hydrogen, i.e. they act as bronsted acids.
`2R-OH+2Na to 2RONa+H_(2)`
The acidic character of alcohols is due to the polar nature of O-H bond.
Number of electron releasing alkyl groups decreases the acidity of the alcohols.
Thus the acidic character decreases as `underset("Primary")(RCH_(2)OH) gt underset("Secondary")(R_(2)CHOH) gt underset("Tertiary")(R_(3)C-OH)`
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SUBHASH PUBLICATION-ALCOHOLS, PHENOLS AND ETHERS-QUESTIONS
  1. The boiling points of alcohols and phenol are high. Give reason.

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  2. How boiling points varies when number of carbon atoms Increases in lin...

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  3. Explain the acidic nature of alcohols.

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  4. Explain the acidic nature of phenols.

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  5. Among alcohols and phenols which one is more acidic ? And why ?

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  6. What is the effect of Electron withdrawing group on acidity of pheno...

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  7. What is the effect of Electron donating group on acidity of alcohol...

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  8. What is the effect of Boiling point of alcohols on increasing numbe...

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  9. What is the effect of the group on the acidity of phenols? CH(3)

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  10. What is the effect of the group on the acidity of phenols? -NO(2)

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  11. Explain esterification reaction with an example.

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  12. What is acetylation reaction? Explain the acetylation of salicylic aci...

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  13. What is Lucas reagent: Give its reaction with primary (1^(@)) and tert...

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  14. Explain the dehydration of primary, secondary and tertiary alcohols.

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  15. Explain the mechanism of dehydration of ethanol

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  16. What happens when 1^(@),2^(@),3^(@) alcohols are passed over heated he...

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  17. Complete the following reactions. RCH(2)OH underset(573K)overset(Cu)...

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  18. Complete the following: CH(3)-CH=CH(2)+H(2)O to .

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  19. Give two methods of conversion of primary alcohol to aldehyde.

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  20. i) Identifiy 'A' and 'B' in the following equations. CH(3)-CH=CH(2) ...

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