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In the following reaction, xA rarryB ...

In the following reaction, `xA rarryB`
`log_(10)[-(d[A])/(dt)]=log_(10)[(d([B]))/(dt)]+0.3010` ‘A’ and ‘B’ respectively can be:

A

`C_(2)H_(2) and C_(6)H_(6)`

B

`C_(2)H_(4) and C_(4)H_(8)`

C

`N_(2)O_(4) and NO_(2)`

D

n - Butane and iso - butane

Text Solution

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The correct Answer is:
To solve the given problem, we need to analyze the relationship between the rates of change of concentrations of reactants and products in a chemical reaction, as described by the logarithmic equation provided. ### Step-by-Step Solution: 1. **Understanding the Given Equation**: The equation provided is: \[ \log_{10}\left(-\frac{d[A]}{dt}\right) = \log_{10}\left(\frac{d[B]}{dt}\right) + 0.3010 \] Here, \(-\frac{d[A]}{dt}\) represents the rate of decrease of concentration of A, and \(\frac{d[B]}{dt}\) represents the rate of increase of concentration of B. 2. **Rewriting the Constant**: The constant \(0.3010\) can be rewritten as: \[ 0.3010 = \log_{10}(2) \] This means we can express the equation as: \[ \log_{10}\left(-\frac{d[A]}{dt}\right) = \log_{10}\left(\frac{d[B]}{dt} \cdot 2\right) \] 3. **Using Logarithmic Properties**: By applying the property of logarithms that states \(\log_{10}(m) = \log_{10}(n)\) implies \(m = n\), we can equate the arguments: \[ -\frac{d[A]}{dt} = 2 \cdot \frac{d[B]}{dt} \] 4. **Rearranging the Equation**: Rearranging this gives us: \[ \frac{d[A]}{dt} = -2 \cdot \frac{d[B]}{dt} \] This indicates that for every 2 moles of B produced, 1 mole of A is consumed. 5. **Identifying the Stoichiometry**: From the equation, we can deduce the stoichiometry of the reaction: \[ xA \rightarrow yB \quad \text{where } x = 2 \text{ and } y = 1 \] Therefore, the reaction can be represented as: \[ 2A \rightarrow B \] 6. **Evaluating the Options**: Now we need to check the options provided to see which reaction fits the stoichiometry \(2A \rightarrow B\). - **Option 1**: \(C_2H_2 \rightarrow C_6H_6\) (not correct) - **Option 2**: \(2C_2H_4 \rightarrow C_4H_8\) (correct) - **Option 3**: \(N_2O_4 \rightarrow NO_2\) (not correct) - **Option 4**: \(n\)-butane and iso-butane (not correct) The only option that fits the stoichiometry \(2A \rightarrow B\) is **Option 2**. ### Final Answer: The correct answer is **Option 2: \(2C_2H_4 \rightarrow C_4H_8\)**.

To solve the given problem, we need to analyze the relationship between the rates of change of concentrations of reactants and products in a chemical reaction, as described by the logarithmic equation provided. ### Step-by-Step Solution: 1. **Understanding the Given Equation**: The equation provided is: \[ \log_{10}\left(-\frac{d[A]}{dt}\right) = \log_{10}\left(\frac{d[B]}{dt}\right) + 0.3010 ...
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