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10 ml of 1 millimolar surfactant solutio...

10 ml of 1 millimolar surfactant solution forms a monolayer covering `0.24cm^(2)` on a polar substrate.
If the polar head is approximated as a cube. Consider the surfactant is adsorbed only on one face of the cube. What is the edge length of cube? (Answer should be in pm and assume Avogadro's number `=6xx10^(23)` ).

Text Solution

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The correct Answer is:
2

Number of milimoles `=10mlxx10^(-3)M=10^(-2)`
Number of moles `=10^(-5)`
Now, number of molecules `=10^(-5)xx6xx10^(23)=6xx10^(18)`
`because" Surface area occupied by "6xx106(18)" molecules "=0.24cm^(2)`
`because" Surface area occupied by 1 molecule"=(0.24)/(6xx10^(18))cm^(2)=0.04xx10^(-18cm^(2)`
As, it is given that polar head is a cube
So, surface area of cube
`=a^(2)(a="edge length")`
`a^(2)=0.04xx10^(-18)cm^(2)`
`a=2xx10^(-10)cm=2pm`
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