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What do atomic radius and ionic radius r...

What do atomic radius and ionic radius really mean to you?

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Atomic radius is the radius of an atom. It measures the size of an atom. If the element is a metal, then the atomic radius refers to the metallic radius, and if the element is a non-metal, then it refers to the covalent radius. Metallic radius is calculated as half the internuclear distance separating the metal cores in the metallic crystal. For example, the internuclear distance between two adjacent copper atoms in solid copper is 256 pm. Thus, the metallic radius of copper is taken as `(256)/(2) "pm"= 128 "pm"`.Covalent radius is measured as the distance between two atoms when they are found together by a single bond in a covalent molecule. For example, the distance between two chlorine atoms in chlorine molecule is 198 pm. Thus, the covalent radius of chlorine is taken as `(198)/(2)"pm"=99 "pm"` Ionic radius means the radius of an ion (cation or anion). The ionic radii can be calculated by measuring the distances between the cations and anions in ionic crystals.
Since a cation is formed by removing an electron from an atom, the cation has fewer electrons than the parent atom resulting in an increase in the effective nuclear charge. Thus, a cation is smaller than the parent atom. For example, the ionic radius of ion is 95 pm, whereas the atomic radius of `Na^(+)` atom is 186 pm. On the other hand, an anion is larger in size than its parent atom. This is because an anion has the same nuclear charge, but more electrons than the parent atom resulting in an increased repulsion among the electrons and a decrease in the effective nuclear charge. For example, the ionic radius of `F^(–)` ion is 136 pm, whereas the atomic radius of F atom is 64 pm.
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NCERT-CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES-EXERCISE
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  2. Why do elements with similar properties occur in the same group?

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  3. What do atomic radius and ionic radius really mean to you?

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  4. How do atomic radii vary (a) down the group and (b) along the period f...

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  5. What do you understand by isoelectronic species? Name a species that w...

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  6. Consider the following species: N^(3-),O^(2-),F^(ө),Na^(o+),Mg^(2+) ...

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  7. Explain why cations are smaller and anions larger in radii than their ...

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  8. What is the significance of the terms-'isolated gaseous atom' and 'gro...

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  9. Energy of an electron in the ground state of the hydrogen atom is -2.1...

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  10. Among the second period elements the actual ionisation enthalpies are ...

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  11. How would you explain the fact that the first ionisation enthalpy of s...

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  12. What are the various factors due to which the ionisation enthalpy of t...

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  13. The first ionisation enthalpy of group 13 elements are : Explain ...

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  14. Which of the following pairs of elements would have a more negative el...

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  15. Would you expect the second electron gain enthalpy of O as positive, m...

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  16. What is the basic difference between the terms electron gain enthalpy ...

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  17. How would you react to the statement that the electronegativity of N o...

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  18. Describe the theory associated with the radius of an atom as it a. g...

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  20. What are the major differences between metals and non-metals?

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