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Write the Lewis dot structure of the nit...

Write the Lewis dot structure of the nitrite ion `(NO_(2)^(Θ))` .

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Step 1. Count the total number of valence electrons of the nitrogen atom, the oxygen atoms and the additional one negative charge (equal to one electron).
`N(2s^(2) 2p^(3)), O (2s^(2) 2p^(4))`
5 + (2 × 6) +1 = 18 electrons ltbvrgt Step 2. The skeletal structure of `NO_(2) ^(-)` is written as : O N O
Step 3. Draw a single bond (one shared electron pair) between the nitrogen and each of the oxygen atoms completing the octets on oxygen atoms. This, however, does not complete the octet on nitrogen if the remaining two electrons constitute lone pair on it
`[:underset(..)overset (..)O" " :overset(..)N:" " overset(..)underset(..)O:]^(-)`
Hence we have to resort to multiple bonding between nitrogen and one of the oxygen atoms (in this case a double bond). This leads to the following Lewis dot structures.
`[:underset(..)overset (..)O" " :overset(..)N:" " overset(..)underset(..)O:]^(-)`
or `[underset(..)overset(..)O=overset(..)N-overset(..)underset(..)O:]^(-)" or " [:underset(..)overset(..)O-overset(..)N=overset(..)underset(..)O]^(-)`
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NCERT-CHEMICAL BONDING AND MOLECULAR STRUCTURE-EXERCISE
  1. Write the Lewis dot structure of the nitrite ion (NO(2)^(Θ)) .

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  2. Explain the formation of a chemical bond.

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  3. Write Lewis dot symbols for atoms of the following elements: Mg,Na,B,O...

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  4. Write Lewis symbols for the following atoms and ions: S and S^(2-), ...

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  5. Draw the Lewis structures for the following molecules and ions: H(2)...

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  6. Define octet rule. Write its significance and limitations.

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  7. Write the favourable factors for the formation of ionic bond.

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  8. Discuss the shape of the following molecules using the VSEPR model: ...

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  9. Although geometries of NH(3) and H(2)O molecules are distorted tetrahe...

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  10. How do you express the bond strength in terms of bond order?

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  11. Define the bond length.

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  12. Explain the important aspects of resonance with reference to the CO(3)...

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  13. H(3)PO(3) can be represented by structure (a) and (b) shown below. Can...

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  14. Write the resonance structures for SO(3),NO(2), and NO(3)^(ө).

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  15. Use Lewis symbols to show electron transfer between the following atom...

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  16. Although both CO(2) and H(2)O are triatomic molecules, the shape of H(...

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  17. Write the significance/applications of dipole moment

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  18. Define electronegativity. How does it differ from electron gain enthal...

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  19. Explain with the help of suitable example polar covalent bond.

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  20. Arrange the bonds in order of increasing ionic character in the molecu...

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  21. The skeletal structure of CH(3)COOH as shown below is correct, but som...

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