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What happens when (a) Borax is heated ...

What happens when
(a) Borax is heated strongly,
(b) Boric acid is added to water,
(c) Aluminium is treated with dilute NaOH,
(d) `BF_(3)` is reacted with ammonia ?

Text Solution

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(a) When heated, borax undergoes various transitions. It first loses water molecules and swells. Then, it turns into a transparent liquid, solidifying to form a glass-like material called borax bead.
`underset("Borax")underset()(Na_(2)B_(4)O_(7).10H_(2))Ooverset(Delta)rarrunderset("metaborate")underset("Sodium")underset()(Na_(2)B_(4)O_(7))overset(Delta)rarr2NaBO_(2)+underset("anhydride")underset("Boric")underset()(B_(2)O_(3))`
(b) When boric acid is added to water, it accepts electrons from `.^(–)OH` ion.
`B(OH)_(3)+2HOHrarr[B(OH)_(4)]^(-)+H_(3)O^(+)`
(c) Al reacts with dilute NaOH to form sodium tetrahydroxoaluminate(III). Hydrogen gas is liberated in the process.
`2Al_((s))+2NaOH_((aq))+6H_(2)O_((l))rarr2Na^(+)[Al(OH)_(4)]_((aq))^(-)+3H_(2(g))`
(d) `BF_(3)` (a Lewis acid) reacts with `NH_(3)` (a Lewis base) to form an adduct. This results in a complete octet around B in `BF_(3)`.
`F_(3)B+:NH_(3)rarrF_(3)Blarr:NH_(3)`
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NCERT-THE P-BLOCK ELEMENTS -EXERCISE
  1. How is excessive content of CO(2) responsible for global warming?

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  2. Explain structures of diborane and boric acid.

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  3. What happens when (a) Borax is heated strongly, (b) Boric acid is ...

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  4. Explain the following reactions (a) Silicon is heated with methyl ch...

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  5. Give reasons : (i) Conc. HNO(3) can be transported in aluminium con...

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  6. Explain why is there a phenomenal decrease in ionisation enthalpy from...

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  7. How would you explain the lower atomic radii of Ga as compared to Al?

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  8. What are allotropes? Sketch the structure of two allotropes of carbon ...

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  9. a. Classify following oxides as neutral, acidic, basic or amphoteric: ...

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  10. In some of the reactions, thallium resembles aluminium whereas in othe...

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  11. When metal X is treated with sodium hydroxide, a white precipitate (A)...

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  12. What do you understand by (a) inert pair effect (b) allotropy and (c...

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  13. A certain salt (X) gives the following tests : (a) Its aqueous solut...

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  14. Write balanced equations for: a.BF(3)+LiHto b.B(2)H(6)+H(2)Oto c...

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  15. Give one method for industrial preparation and one for laboratory prep...

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  16. Oxides formed by p-block elements may be (i) basic (ii) acidic (...

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  17. Boric acid is polymeric due to

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  18. The type of hybridisation of boron in diborane is (a) sp , (b) sp^(...

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  19. Thermodynamically the most stable form of carbon is (a) diamond , (b...

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  20. Elements of group 14 (a) exhibit oxidation state of +4 only (b) ex...

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