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Among the given pairs in which pairs fir...

Among the given pairs in which pairs first compound has higher boiling point than second?

A

`CH_(3)-overset(o+)CH-CH_(3) and CH_(3) -overset(o+)CH-OCH_(3)`

B

`CH_(3)-CH_(2)-CH_(2)-CH_(3)and CH_(3)-CH_(2)-CH_(3)`

C

`CH_(3)-CH_(2)-CH_(2)-CH_(2)-CH_(3)and CH_(3)-overset(CH_(2)-CH_(3))overset(|)(C)-H-CH_(2)-OH`

D

`CH_(3)-CH_(2)-CH_(2)-CH_(3)and CH_(3)-CH_(2)-CH_(2)-CI`

Text Solution

Verified by Experts

The correct Answer is:
B

B.P `prop` surface area of molecule `prop` extent of inter molecular H-bonding `prop` dipole moment of molecules.
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