Which of the following reactions is not ...

Which of the following reactions is not exothermic?

`CH_(3)-CI+CH_(3)-CH_(3)rarrCH_(4)+CH_(3)-CH_(2-CI`

`CH_(3)-CI+(CH_(3))_(3)C-HrarrCH_(4)+(CH_(3))_(3)C-CI`

`CH_(3)-CI+CH_(2)=CH-CH_(3)rarrCH_(4)+CH_(2)=CH-CH_(2)-CI`

`CH_(3)-CI+CH_(2)=CH_(2)rarrCH_(4)+CH_(2)=CHCI`

Verified by Experts

The correct Answer is:

`{:(H_(2)=CH-HrarrH_(2)C=overset(*)CH),(" "uarr" " "unstable vinyl radical"),("string bond"):}`
thereofore it is endothermic .

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