`pHK_(a) prop (1)/("acidic strength") prop -I` effect of attached groups
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CH_(3)-CH_(2)-CH_(2)-O-CH_(3) and CH_(3)-overset(CH_(3))overset(|)(C )H-O-CH_(3) are
H_(3)C-overset(O)overset(||)(C)-CH_(2)CH_(2)CO_(2)CH_(3) to H_(3)C-overset(OH)overset(||)(CH)-CH_(2)CH_(2)CH_(2)OH can be effected using:
H_(3)C-overset(O)overset(||)(C)-CH_(2)CH_(2)CO_(2)CH_(3) to H_(3)C-overset(OH)overset(||)(CH)-CH_(2)CH_(2)CH_(2)OH can be effected using:
An amino acid may be represented by general formula H_(2)N overset(R)overset(|)(CH)-COOH . If R = -CH_(2)C_(6)H_(5) then it is phenylalanine (Phe) and if R = CH_(3) then it is alanine (Ala). Find the sequence of reagents from those given below to synthesize Phe-Ala. (1) ZNHoverset(CH_(3))overset(|)(CH)CO_(2)H , (2) H_(2)N overset(CH_(3))overset(|)(CH)CO_(2)CH_(2)C_(6)H_(5) (3) ZNHoverset(CH_(2)C_(6)H_(5))overset(|)(CH)CO_(2)H (4) H_(2)N overset(CH_(2)C_(6)H_(5))overset(|)(CH)CO_(2)CH_(2)C_(6)H_(5)
Consider the following carbocation- (a). CH_(3)-overset(o+)(C)H_(2) (b). CH_(2)=overset(o+)(C)H (c). CH_(2)=CH-overset(o+)(C)H_(2) (d). C_(6)H_(5)-Coverset(o+)(H)_(2)