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Which of the following belongs to +I gr...

Which of the following belongs to `+I` group ?

A

`-OH`

B

`-OCH_(3)`

C

`-COOH`

D

`-CH_(3)`

Text Solution

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The correct Answer is:
To determine which of the following groups belongs to the +I (positive inductive) group, we need to understand the concept of inductive effects in organic chemistry. ### Step-by-Step Solution: 1. **Understand Inductive Effects**: Inductive effects are the permanent effects that occur due to the electronegativity difference between atoms in a molecule. There are two types: +I (electron-donating) and -I (electron-withdrawing). 2. **Identify +I Effect**: The +I effect is exhibited by groups that donate electrons to the rest of the molecule. These groups are typically less electronegative than carbon or have no electronegativity difference that would cause electron withdrawal. 3. **Identify -I Effect**: The -I effect is exhibited by groups that withdraw electrons from the rest of the molecule. These groups are usually highly electronegative atoms or groups (like F, Cl, Br, NO2, etc.) that pull electron density away from the carbon atom. 4. **Analyze the Given Groups**: - **Hydroxyl Group (OH)**: This group is electronegative and pulls electron density towards itself, thus exhibiting -I effect. - **Methoxy Group (OCH3)**: Similar to OH, the oxygen is electronegative and withdraws electron density, thus exhibiting -I effect. - **Carboxyl Group (COOH)**: The carbon in this group is bonded to an electronegative oxygen, which pulls electron density, thus exhibiting -I effect. - **Methyl Group (CH3)**: This group does not have a highly electronegative atom and can donate electron density to the carbon atom, thus exhibiting +I effect. 5. **Conclusion**: Among the groups analyzed, the methyl group (CH3) is the only one that belongs to the +I group as it donates electrons. ### Final Answer: The group that belongs to the +I group is the **Methyl Group (CH3)**.

To determine which of the following groups belongs to the +I (positive inductive) group, we need to understand the concept of inductive effects in organic chemistry. ### Step-by-Step Solution: 1. **Understand Inductive Effects**: Inductive effects are the permanent effects that occur due to the electronegativity difference between atoms in a molecule. There are two types: +I (electron-donating) and -I (electron-withdrawing). 2. **Identify +I Effect**: The +I effect is exhibited by groups that donate electrons to the rest of the molecule. These groups are typically less electronegative than carbon or have no electronegativity difference that would cause electron withdrawal. ...
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HIMANSHU PANDEY-GENERAL ORGANIC CHEMISTRY-Subjective Type Problems
  1. Which of the following belongs to +I group ?

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  2. Which of the following systems are conjugated?

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  3. Draw all reasonable resonance structures for each species.

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  4. Draw all reasonable resonance structures for each species.

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  5. Determine the hybridization at the carbon atom indicated in each speci...

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  6. Explain each statement using resonance theory. (a) The indicated C-...

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  7. Rank the following dienes in order of increasin heat of hydrogenation.

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  8. How many pi electrons are contained in each molecule ?

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  9. Which compaounds are aromatic? For any compound that is not aromatic, ...

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  10. Which of the following heterocycles are aromatic?

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  11. Lebel each compound as aromatic, antiaromatic, or not aromatic. Assume...

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  12. Hydrocarbons A and B both possess a significant dipolel, even though e...

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  13. Rank the indicated C-C bonds in order of increasing bond length, and e...

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  14. The purine heterocycle occurs commonly in the structure of DNA. (a) ...

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  15. (a) How many pi electrons does C contion? (b) How many pi electrons ...

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  16. Draw additional resonance structure for each species.

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  17. The carbon-carbon bond lengths in naphthalene are not equal. Use a res...

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  18. Which compound in each pair is the stronger acid?

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  19. Treatment of indene with NaNH(2) forms its conjugate base in a Bronste...

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  20. Draw the conjugate bases of pyrrole and cyclopentadiene. Explain why t...

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