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The species CH(3)overset(+)CHCH(3) is le...

The species `CH_(3)overset(+)CHCH_(3)` is less stable than :

A

`(CH_(3))_(3)C^(+)`

B

`CH_(3)CH_(2)overset(+)CH_(2)`

C

`CH_(3)overset(+)CH_(2)`

D

`CH_(3)^(+)`

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The correct Answer is:
To determine which species is more stable than the given carbocation \( CH_3^+CHCH_3 \), we need to analyze the stability of carbocations based on hyperconjugation and inductive effects. ### Step-by-Step Solution: 1. **Identify the Given Carbocation:** The given species is \( CH_3^+CHCH_3 \), which is a secondary carbocation. It has one positive charge on the carbon that is bonded to two methyl groups and one hydrogen. 2. **Evaluate the Stability Factors:** - **Hyperconjugation:** This involves the interaction of the empty p-orbital of the carbocation with the filled orbitals of adjacent C-H bonds. Each methyl group contributes to hyperconjugation. - **Inductive Effect:** Alkyl groups are electron-donating through the inductive effect, which can help stabilize the positive charge. 3. **Count the Alpha Hydrogens:** In the given carbocation: - There are 6 alpha hydrogens (3 from each methyl group). - This allows for some hyperconjugation, but it is not the most stable configuration. 4. **Compare with Other Carbocations:** - **Tertiary Carbocation:** A carbocation with three alkyl groups (e.g., \( (CH_3)_3C^+ \)) would have 9 alpha hydrogens contributing to hyperconjugation. This makes it more stable than the given carbocation. - **Primary Carbocation:** A primary carbocation (e.g., \( CH_3CH_2^+ \)) is less stable than the secondary carbocation due to fewer hyperconjugation and inductive effects. 5. **Conclusion:** The species \( CH_3^+CHCH_3 \) is less stable than a tertiary carbocation \( (CH_3)_3C^+ \) due to the higher number of alpha hydrogens and stronger hyperconjugation in the tertiary carbocation. ### Final Answer: The species \( CH_3^+CHCH_3 \) is less stable than \( (CH_3)_3C^+ \).

To determine which species is more stable than the given carbocation \( CH_3^+CHCH_3 \), we need to analyze the stability of carbocations based on hyperconjugation and inductive effects. ### Step-by-Step Solution: 1. **Identify the Given Carbocation:** The given species is \( CH_3^+CHCH_3 \), which is a secondary carbocation. It has one positive charge on the carbon that is bonded to two methyl groups and one hydrogen. 2. **Evaluate the Stability Factors:** ...
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HIMANSHU PANDEY-GENERAL ORGANIC CHEMISTRY-Subjective Type Problems
  1. The species CH(3)overset(+)CHCH(3) is less stable than :

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  2. Which of the following systems are conjugated?

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  3. Draw all reasonable resonance structures for each species.

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  4. Draw all reasonable resonance structures for each species.

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  5. Determine the hybridization at the carbon atom indicated in each speci...

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  6. Explain each statement using resonance theory. (a) The indicated C-...

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  7. Rank the following dienes in order of increasin heat of hydrogenation.

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  8. How many pi electrons are contained in each molecule ?

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  9. Which compaounds are aromatic? For any compound that is not aromatic, ...

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  10. Which of the following heterocycles are aromatic?

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  11. Lebel each compound as aromatic, antiaromatic, or not aromatic. Assume...

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  12. Hydrocarbons A and B both possess a significant dipolel, even though e...

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  13. Rank the indicated C-C bonds in order of increasing bond length, and e...

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  14. The purine heterocycle occurs commonly in the structure of DNA. (a) ...

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  15. (a) How many pi electrons does C contion? (b) How many pi electrons ...

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  16. Draw additional resonance structure for each species.

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  17. The carbon-carbon bond lengths in naphthalene are not equal. Use a res...

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  18. Which compound in each pair is the stronger acid?

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  19. Treatment of indene with NaNH(2) forms its conjugate base in a Bronste...

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  20. Draw the conjugate bases of pyrrole and cyclopentadiene. Explain why t...

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