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Consider the following species : (A)ov...

Consider the following species :
(A)`overset(Ɵ)OH`
(B)`CH_(3)-overset(Ɵ)O`
(C) `overset(Ɵ)CH_(3)`
(D) `overset(Ɵ)NH_(2)`

A

`CgtDgtAgtB`

B

`BgtAgtCgtD`

C

`AgtBgtCgtD`

D

`CgtAgtBgtD`

Text Solution

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The correct Answer is:
A
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Consider the species. overset(Θ)OH CH_(3)-overset(overset(Θ)O overset(Θ)CH_(3) overset(Θ)NH_(2) Arrange these nucleophilic species in their decreasing order of nucleophilicity :

Arrange nucleophilicity of given species in decreasing order: (1) CH_(3)-overset(ө)CH_(2) (2) CH_(3)-overset(ө)O (3) overset(ө)NH_(2) (4) overset(ө)F

Which H atom in the following ester is most acidic ? overset(1)(CH_(3))-overset(2)(CH_(2))-overset(O)overset(||)(C)-overset(3)(CH_(2))-overset(O)overset(||)(C)-O-overset(4)(CH_(2))overset(5)(CH_(3))

Consider the following reaction: CH_(3)-overset(O)overset(||)(C)-OH+CH_(3)-OH overset(H^(o+))hArrCH_(3)-overset(O)overset(||)(C)-O-CH_(3)+HOH True about the reaction is:

The correct stability order for the following is {:(CH_(3)-CH_(2)-overset(ɵ)(C)H_(2),CH_(3)-overset(ɵ)(C)H-CH_(3),Cl-CH_(2)-overset(ɵ)(C)H_(2),Ph-overset(ɵ)(C)H_(2)),(I,II,III,IV):}

Compare the stabilities of the following corbocation (a) overset(+)CH_(2) overset(..)(NH_(2)) " "(b) overset(+) CH_(2) - underset(..)overset(..)(OH) " "(c) overset(+) CH_(2) - underset(..) overset(..)F:

Which of the following are isoelectronic species ? overset(o+)(CH_(3))(I), overset(ɵ)(NH_(2))(II), overset(o+)(NH_(4))(III) and NH_(3) (IV)

HIMANSHU PANDEY-GENERAL ORGANIC CHEMISTRY-Subjective Type Problems
  1. Consider the following species : (A)overset(Ɵ)OH (B)CH(3)-overset(...

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  2. Which of the following systems are conjugated?

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  3. Draw all reasonable resonance structures for each species.

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  4. Draw all reasonable resonance structures for each species.

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  5. Determine the hybridization at the carbon atom indicated in each speci...

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  6. Explain each statement using resonance theory. (a) The indicated C-...

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  7. Rank the following dienes in order of increasin heat of hydrogenation.

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  8. How many pi electrons are contained in each molecule ?

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  9. Which compaounds are aromatic? For any compound that is not aromatic, ...

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  10. Which of the following heterocycles are aromatic?

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  11. Lebel each compound as aromatic, antiaromatic, or not aromatic. Assume...

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  12. Hydrocarbons A and B both possess a significant dipolel, even though e...

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  13. Rank the indicated C-C bonds in order of increasing bond length, and e...

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  14. The purine heterocycle occurs commonly in the structure of DNA. (a) ...

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  15. (a) How many pi electrons does C contion? (b) How many pi electrons ...

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  16. Draw additional resonance structure for each species.

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  17. The carbon-carbon bond lengths in naphthalene are not equal. Use a res...

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  18. Which compound in each pair is the stronger acid?

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  19. Treatment of indene with NaNH(2) forms its conjugate base in a Bronste...

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  20. Draw the conjugate bases of pyrrole and cyclopentadiene. Explain why t...

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