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In the given reaction [X] will be : C(...

In the given reaction [X] will be :
`C_(6)H_(5)-underset(O)underset(||)C-Hoverset(NH_(2)OH//H^(o+))rarr [X]`

A

only syn oxime

B

only anti oxime

C

mixture of syn and anti oxime

D

secondary amide

Text Solution

AI Generated Solution

The correct Answer is:
To determine the product [X] in the given reaction, we will analyze the reaction step by step. ### Step 1: Identify the Reactants The reactant is a carbonyl compound, specifically an aldehyde, which is represented as: \[ C_6H_5 - C(=O) - H \] This is benzaldehyde (C6H5CHO). ### Step 2: Identify the Reagent The reagent used in the reaction is hydroxylamine (NH2OH) in the presence of an acid (H+). Hydroxylamine is known to react with aldehydes and ketones to form oximes. ### Step 3: Reaction Mechanism When benzaldehyde reacts with hydroxylamine, the carbonyl group (C=O) of the aldehyde will react with the nitrogen of hydroxylamine. The reaction proceeds as follows: 1. The nitrogen atom of hydroxylamine attacks the carbon atom of the carbonyl group. 2. A tetrahedral intermediate is formed. 3. A molecule of water (H2O) is eliminated in a condensation reaction. ### Step 4: Product Formation After the elimination of water, the product formed is an oxime. The structure of the oxime can be represented as: \[ C_6H_5 - C(=N - OH) - H \] This indicates that the carbon atom is now double-bonded to nitrogen instead of oxygen. ### Step 5: Geometric Isomers The oxime can exist in two geometric isomers due to the presence of the double bond between carbon and nitrogen: 1. **Z (cis) isomer**: where the phenyl group (C6H5) and the hydroxyl group (OH) are on the same side. 2. **E (trans) isomer**: where the phenyl group (C6H5) and the hydroxyl group (OH) are on opposite sides. ### Conclusion The product [X] will be a mixture of both the Z and E isomers of the oxime. Thus, the final answer is: **[X] is a mixture of Z and E oximes.**
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HIMANSHU PANDEY-CARBONYL COMPOUNDS-Level 1 (Q.26 To Q.50)
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  4. Which will be give silver mirror test with Tollen's reagent?

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  8. Schiff's reagent gives pink colour with :

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  15. Which of the following compounds are in their most stable tautomeric f...

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  18. Most stable Tautomer of the following compound is :

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  19. underset((ii)C(6)H(5)Ona)overset((i)Br(2),H^(+))rarr P,P will be

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  20. Which of the following is an example of aldol condensation ?

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