Home
Class 12
CHEMISTRY
When an aldehyde with no alpha-hydrogen...

When an aldehyde with no `alpha`-hydrogen react with concentrated aqueous NaOH, half the aldehyde is converted ot carboxylic acid salt and other half is converted to an alcoho. In other words, half the reaction is oxidized and other half is reduced. This reaction is known as Cannizzaro reaction


Find out the products of following reaction :

X and Y are :

A

`Ph-overset(O)overset(||)C-overset(Ө)O` and `CH_(3)OH`

B

`Ph-CH_(2)OH` and `H-overset(O)overset(||)C-overset(Ө)O`

C

`Ph-CH_(2)OH` and `CH_(3)OH`

D

`Ph-overset(O)overset(||)C-overset(Ө)O` and `H-overset(O)overset(||)C-overset(Ө)O`

Text Solution

Verified by Experts

The correct Answer is:
B
Promotional Banner

Topper's Solved these Questions

  • CARBONYL COMPOUNDS

    HIMANSHU PANDEY|Exercise Linked Comprehension Type (Q.26 To Q.33)|8 Videos
  • CARBONYL COMPOUNDS

    HIMANSHU PANDEY|Exercise Match The Column|11 Videos
  • CARBONYL COMPOUNDS

    HIMANSHU PANDEY|Exercise More Than One Correct (Q.26 To Q.50)|25 Videos
  • CABOXYLIC ACIDS AND ITS DERIVATIVES

    HIMANSHU PANDEY|Exercise Subjective Type Problems|8 Videos
  • CHEMISTRY IN DAILY LIFE

    HIMANSHU PANDEY|Exercise Integer Answer Type Problems|7 Videos

Similar Questions

Explore conceptually related problems

When an aldehyde with no alpha -hydrogen react with concentrated aqueous NaOH, half the aldehyde is converted ot carboxylic acid salt and other half is converted to an alcoho. In other words, half the reaction is oxidized and other half is reduced. This reaction is known as Cannizzaro reaction Find out 'X'of the reaction :

When an aldehyde with no alpha -hydrogen react with concentrated aqueous NaOH, half the aldehyde is converted ot carboxylic acid salt and other half is converted to an alcoho. In other words, half the reaction is oxidized and other half is reduced. This reaction is known as Cannizzaro reaction Which of the following will not give Cannizzaro reaction ?

A half cell reaction is one that

In Cannizzaro's reaction an aldehyde undergoes

HIMANSHU PANDEY-CARBONYL COMPOUNDS-Linked Comprehension Type (Q.1 To Q.25)
  1. The base catalysed reaction of 1,2-diketone to a salt of 2-hydroxy car...

    Text Solution

    |

  2. When an aldehyde with no alpha-hydrogen react with concentrated aqueo...

    Text Solution

    |

  3. When an aldehyde with no alpha-hydrogen react with concentrated aqueo...

    Text Solution

    |

  4. When an aldehyde with no alpha-hydrogen react with concentrated aqueo...

    Text Solution

    |

  5. When two molecules of an ester undergo a condensation reaction, the re...

    Text Solution

    |

  6. When two molecules of an ester undergo a condensation reaction, the re...

    Text Solution

    |

  7. When two molecules of an ester undergo a condensation reaction, the re...

    Text Solution

    |

  8. A organic compound A has molecular formula C(11)H(14)O.A on treatment ...

    Text Solution

    |

  9. A organic compound A has molecular formula C(11)H(14)O.A on treatment ...

    Text Solution

    |

  10. A organic compound A has molecular formula C(11)H(14)O.A on treatment ...

    Text Solution

    |

  11. A + B underset(Delta)overset(NaOH)rarr Product :

    Text Solution

    |

  12. Find correct structure of E :

    Text Solution

    |

  13. E overset(CF(3)CO(3)H)rarr Product :

    Text Solution

    |

  14. Compound having -overset(O)overset(||)C-CH(3) group reacts rapidly wi...

    Text Solution

    |

  15. Compound having -overset(O)overset(||)C-CH(3) group reacts rapidly wi...

    Text Solution

    |

  16. Compound having -overset(O)overset(||)C-CH(3) group reacts rapidly wi...

    Text Solution

    |

  17. Identify correct structure of 'Y' :

    Text Solution

    |

  18. Find out structure of final product P :

    Text Solution

    |

  19. Y underset(H(2)O(2),""^(Ө)OH)overset(BD(3),THF)rarr product Find out...

    Text Solution

    |

  20. An organic compound (A) C(8)H(10)O was subjected to a series of test ...

    Text Solution

    |