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What is meant by disproportionation of a...

What is meant by disproportionation of an oxidation state ? Give an example

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When a particular oxidation state becomes less stable relative to other oxidation states, one lower, one higher, it is said to undergo disproportionation. For example, manganese (VI) becomes unstable relative to manganese(VII) and manganese (IV) in acidic solution.
`3Mn^(VI)O_(4)^(2-)+4H^(+)to2Mn^(VII)O_(4)^(-)+Mn^(IV)O_(2)+2H_(2)O`
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NCERT-THE D AND F BLOCK ELEMENTS-Exercise
  1. What is meant by disproportionation of an oxidation state ? Give an e...

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  2. Write down the electronic configuration of: (i). Cr^(3+) (ii). Pm^...

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  3. Why are Mn^(2+) compounds more stable than Fe^(2+) toward oxidation to...

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  4. Explain briefly how +2 state become more and more stable in the first ...

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  5. To what extent do the electronic configurations, decide the stability ...

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  6. What may be the stable oxidation state of the transition element with ...

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  7. Name the oxometal anions of the first series of the transition metals ...

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  8. What is lanthanoid contraction? What are the consequences of lanthanol...

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  9. What are the characteristics of the transition elements and why are th...

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  10. In what way is the electronic configuration of the transition elements...

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  11. What are the different oxidation states exhibited by the lanthanoids?

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  12. Explain gives reason. (a) Transition metal and many of their compoun...

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  13. What are interstitial compounds? Why are such compounds well known for...

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  14. How is the variability in oxidation states of transition metals differ...

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  15. Describe the preparation of potassium dichromate from iron chromite or...

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  16. Describe the oxidising action of potassium dichromate and write the io...

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  17. Describe the preparation of potassium permanganate. How does the acidi...

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  18. For M^(2+)//M and M^(3+)//M^(2+) systems the E^(ϴ) values for some met...

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  19. Predict which of the following will be coloured in aqueous solution? ...

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  20. Compare the stability of +2 oxidation state for the elements of the fi...

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  21. Compare the chemistry of actinoids with that of the lanthanoids with s...

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