Home
Class 12
CHEMISTRY
A reaction is first order in A secod ord...

A reaction is first order in `A` secod order in `B`:
(i) write differential rate equation.
(ii) How is the rate affected when the concentration of `B` is tripled ?
(iii) How is the rate affected when the concentration of both `A` and `B` is doubled?

Text Solution

Verified by Experts

(i) The differential rate equation will be
`-(d [R])/("dt") = k [A] [B]^(2)`
(ii) If the concentration of B is increased three times , then
`-(d[R])/("dt") = k[A] [3B]^(2)`
= `9* k [ A] [B]^(2)`
Therefore , the rate of reaction will increase 9 times
(iii) When the concentrations of both A and B are doubled ,
`-(d [R])/("dt") = k[A] [B]^(2)`
= `k[2A][2B]^(2)`
= `8*k [A][B]^(2)`
Therefore , the rate of reaction will increase 8 times .
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    NCERT|Exercise Exercise|1 Videos
  • CHEMICAL KINETICS

    NCERT|Exercise SOLVED EXAMPLE|1 Videos
  • BIOMOLECULES

    NCERT|Exercise Exercise|33 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    NCERT|Exercise Exercise|32 Videos

Similar Questions

Explore conceptually related problems

A reaction is first order in A and second order in B i) Write differential rate equation. ii) How is rate affected when the concentration of B is tripled? iii) How is rate affected when the concentration of both A and B are doubled?

A reaction is first order in A and second order in B (i) Write the differential rate equation. (ii) How is the rate affected on increasing the concentation of B three times ? (iii) How is the rate affected when the concentration of both A and B are doubled ?

(a) A reaction is second order in A and first order in B . (i) Write the differential rate equation. (ii) How is the rate affected on increasing the concentration of A three times? (iii) How is the rate affected when the concentration of both A and B doubled? (b) A first order reaction takes 40 minutes for 30% decomposition. Calculate t_(1//2) for this reaction. (Given log 1.428 = 0.1548)

A reaction is first order in A and of second order in B. Write the differential rate equation for the reaction.

A reaction is first order in A and second order in B : How is the rate affected when the concentrations of both A and B are doubled?

A reaction is first order in A and second order in B . How is rate affected when concentration of B is tripled?