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Halogens have maximum negative gain enth...

Halogens have maximum negative gain enthalpy in the respective periods of the periodic table. Why?

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Halogens have the smallest size in their respective periods and therefore high effective nuclear charge. As a consequence, they readily accept one electron to acquire noble gas electronic configuration.
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Why do halogens have maximum negative electron gain enthalpy in the respective periods of the periodic table?

Be and Ne have positive values of electron gain enthalpy against the general trend in their period in modern periodic table. Explain.

The halogens have the smallest atomic radii in their respective periods. The atomic radius of fluorine is extremely small. All halogens exhibit -1 oxidation state. They are strong oxidising agents and have maximum negative electron gain enthalpy. Among halogens, fluorine shows anomalous behaviour in many properties: For example electronegativity and ionisation enthalpy are higher for fluorine than expected whereas bond dissociation enthalpy, m.p. and b.p.and electron gain enthalpy are quite lower than expected. Halogens react with hydrogen to give hydrogen halides (HX) and combine amongst themselves to form a number of compounds of the type XX', XX'_(3), XX'_(5) and XX'_(7) called inter halogens. Why halogens have maximum negative electron gain enthalpy?

Discuss the factors affecting electron gain enthalpy and the trend in its variation in the periodic table.

NCERT-THE P-BLOCK ELEMENTS-EXERCISE
  1. Halogens have maximum negative gain enthalpy in the respective periods...

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  2. Why are pentahalides of P,As,Sb and Bi are more covalent than trihalid...

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  3. Why is BiH3 the strongest reducing agent amongst all the hydrides of g...

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  4. Why is N(2) less reactive at room temperature ?

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  5. Mention the conditions required to maximise the yield of ammonia.

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  6. How does ammonia react with a solution of Cu^(2+)?

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  7. What is the covalence of nitrogen in N2O5?

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  8. Bond angle in PH(4)^(+) is higher than that in PH(3).Why ?

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  9. What happens when white phosphorus is heated with concentrated NaOH so...

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  10. What happens when PCl(5) is heated?

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  11. Write a balanced equation for the reaction of PCl5 in heavy water.

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  12. What is the basicity of H(3)PO(4) ?

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  13. What happens when H(3)PO(3) is heated.

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  14. List the important sources of sulphur.

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  15. Write the order of thermal stability of the hydrides of group 16 eleme...

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  16. Why is H(2)O a liquid and H(2)S a gas?

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  17. Which of the following does not react with oxygen directly? Zn,Ti,Pt,F...

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  18. Complete the following reactions: (i) C(2) H(4) + O(2) to (ii)...

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  19. Why does O3 act as a powerful oxidising agent?

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  20. How is O(3) estimated quantitatively ?

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  21. What happens when sulphur dioxide is passed through an aqueous solutio...

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