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Discuss the molecular shape of BrF(3) on...

Discuss the molecular shape of `BrF_(3)` on the basis of `VSEPR` theory.

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The central atom Br has seven electrons in the valence shell. Three of these will form electronpair bonds with three fluorine atoms leaving behind four electrons. Thus, there are three bond pairs and two lone pairs. According to VSEPR theory, these will occupy the corners of a trigonal bipyramid. The two lone pairs will occupy the equatorial positions to minimise lone pair-lone pair and the bond pairlone pair repulsions which are greater than the bond pair-bond pair repulsions. In addition, the axial fluorine atoms will be bent towards the equatorial fluorine in order to minimise the lone-pair-lone pair repulsions. The shape would be that of a slightly bent ‘T’.
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NCERT-THE P-BLOCK ELEMENTS-EXERCISE
  1. Discuss the molecular shape of BrF(3) on the basis of VSEPR theory.

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  2. Why are pentahalides of P,As,Sb and Bi are more covalent than trihalid...

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  3. Why is BiH3 the strongest reducing agent amongst all the hydrides of g...

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  4. Why is N(2) less reactive at room temperature ?

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  5. Mention the conditions required to maximise the yield of ammonia.

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  6. How does ammonia react with a solution of Cu^(2+)?

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  7. What is the covalence of nitrogen in N2O5?

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  8. Bond angle in PH(4)^(+) is higher than that in PH(3).Why ?

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  9. What happens when white phosphorus is heated with concentrated NaOH so...

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  10. What happens when PCl(5) is heated?

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  11. Write a balanced equation for the reaction of PCl5 in heavy water.

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  12. What is the basicity of H(3)PO(4) ?

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  13. What happens when H(3)PO(3) is heated.

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  14. List the important sources of sulphur.

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  15. Write the order of thermal stability of the hydrides of group 16 eleme...

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  16. Why is H(2)O a liquid and H(2)S a gas?

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  17. Which of the following does not react with oxygen directly? Zn,Ti,Pt,F...

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  18. Complete the following reactions: (i) C(2) H(4) + O(2) to (ii)...

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  19. Why does O3 act as a powerful oxidising agent?

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  20. How is O(3) estimated quantitatively ?

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  21. What happens when sulphur dioxide is passed through an aqueous solutio...

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