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Why is K(a(2)) ltlt K(a(1)) for H(2) ...

Why is `K_(a_(2)) ltlt K_(a_(1))` for `H_(2) SO_(4)` in water ?

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`H_(2) SO_(4(aq)) + H_(2) O_((l)) to H_(3)O_((aq))^(+) + HSO_(4(aq))^(-), K_(a_(1)) gt 10`
`H_(2) SO_(4(aq))^(-) + H_(2) O_((l)) to H_(3)O_((aq))^(+) + SO_(4(aq))^(-)," " K_(a_(2)) = 1.2 xx 10^(-2)`
It can be noticed that `K_(a_(1)) gt gt K_(a_(2))`
This is because a neutral `H_(2)SO_(4)` has a much higher tendency to lose a proton than the negatively charged `HSO_(4)^(-)`. Thus, the former is a much stronger acid than the latter.
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NCERT-THE P-BLOCK ELEMENTS-EXERCISE
  1. Mention three areas in which H2SO4 plays an important role.

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  2. Write the conditions to maximise the yield of H2SO4 by contact process...

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  3. Why is K(a(2)) ltlt K(a(1)) for H(2) SO(4) in water ?

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  4. Considering the parameters such as bond dissociation enthalpy, electro...

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  5. Give two examples to show the anomalous behavious of fluorine.

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  6. Sea is the greatest source of some halogens. Comment.

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  7. Give the reason for bleaching action of Cl2.

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  8. Name two poisonous gases which can be prepared from chlorine gas.

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  9. Why is ICI more reactive than I2?

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  10. Why is helium used in diving apparatus?

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  11. Balance the following equation: XeF6+H2OtoXeO2F2+HF

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  12. Why has it been difficult to study the chemistry of radon?

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  13. Discuss the general characteristics of Group 15 elements with referenc...

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  14. Why does the reactivity of nitrogen differ from phosphorus?

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  15. Discuss the trends in chemical reactivity of group 15 elements.

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  16. Why does NH3 form hydrogen bond but PH3 does not?

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  17. How is nitrogen prepared in the laboratory? Write the chemical equatio...

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  18. How is ammonia manufactured industrially?

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  19. Illustrate how copper metal can give different product on reaction wit...

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  20. Give the resonating structures of NO(2) and N(2)O(5).

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