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Considering the parameters such as bond dissociation enthalpy, electron gain enthalpy and hydration enthalpy, compare the oxidising power of `F_(2) and Cl_(2)`

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Fluorine is a much stronger oxidizing agent than chlorine. The oxidizing power depends on three factors.
1. Bond dissociation energy
2. Electron gain enthalpy
3. Hydration enthalpy
The electron gain enthalpy of chlorine is more negative than that of fluorine. However, the bond dissociation energy of fluorine is much lesser than that of chlorine. Also, because of its small size, the hydration energy of fluorine is much higher than that of chlorine. Therefore, the latter two factors more than compensate for the less negative electron gain enthalpy of fluorine. Thus, fluorine is a much stronger oxidizing agent than chlorine.
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NCERT-THE P-BLOCK ELEMENTS-EXERCISE
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  2. Why is K(a(2)) ltlt K(a(1)) for H(2) SO(4) in water ?

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  3. Considering the parameters such as bond dissociation enthalpy, electro...

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  4. Give two examples to show the anomalous behavious of fluorine.

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  5. Sea is the greatest source of some halogens. Comment.

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  6. Give the reason for bleaching action of Cl2.

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  7. Name two poisonous gases which can be prepared from chlorine gas.

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  8. Why is ICI more reactive than I2?

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  9. Why is helium used in diving apparatus?

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  10. Balance the following equation: XeF6+H2OtoXeO2F2+HF

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  11. Why has it been difficult to study the chemistry of radon?

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  12. Discuss the general characteristics of Group 15 elements with referenc...

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  13. Why does the reactivity of nitrogen differ from phosphorus?

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  14. Discuss the trends in chemical reactivity of group 15 elements.

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  15. Why does NH3 form hydrogen bond but PH3 does not?

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  16. How is nitrogen prepared in the laboratory? Write the chemical equatio...

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  17. How is ammonia manufactured industrially?

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  18. Illustrate how copper metal can give different product on reaction wit...

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  19. Give the resonating structures of NO(2) and N(2)O(5).

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  20. The HNH angle value is higher than HPH, HAsH and HSbH angles. Why?

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