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Why does the reactivity of nitrogen diff...

Why does the reactivity of nitrogen differ from phosphorus?

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Nitrogen is chemically less reactive. This is because of the high stability of its molecule, `N_(2)`. In `N_(2)`, the two nitrogen atoms form a triple bond. This triple bond has very high bond strength, which is very difficult to break. It is because of nitrogen’s small size that it is able to form`ppi−ppi` bonds with itself. This property is not exhibited by atoms such as phosphorus. Thus, phosphorus is more reactive than nitrogen.
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NCERT-THE P-BLOCK ELEMENTS-EXERCISE
  1. Why has it been difficult to study the chemistry of radon?

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  2. Discuss the general characteristics of Group 15 elements with referenc...

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  3. Why does the reactivity of nitrogen differ from phosphorus?

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  4. Discuss the trends in chemical reactivity of group 15 elements.

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  5. Why does NH3 form hydrogen bond but PH3 does not?

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  6. How is nitrogen prepared in the laboratory? Write the chemical equatio...

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  7. How is ammonia manufactured industrially?

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  8. Illustrate how copper metal can give different product on reaction wit...

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  9. Give the resonating structures of NO(2) and N(2)O(5).

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  10. The HNH angle value is higher than HPH, HAsH and HSbH angles. Why?

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  11. Why does R3P=O exist but R3N=O does not (R= alkyl group)?

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  12. Explain why NH(3) is basic while BiH(3) is only feebly basic ?

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  13. Nitrogen exists as diatomic molecule and phosphorus as P(4). Why ?

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  14. Write main differences between the properties of white phosphorus and ...

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  15. Why does nitrogen show catenation properties less than phosphorus.

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  16. Give the disproportionation reaction of H3PO3.

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  17. Can PCl5 act as an oxidising as well as a reducing agent? Justify.

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  18. Justify the placement of O, S, Se, Te and Po in the same group of the ...

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  19. Why is dioxygen a gas but sulphur a solid?

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  20. Knowing the electron gain enthalpy values for O rarr O^(Ө) and O rarr ...

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