Home
Class 12
CHEMISTRY
Explain why NH(3) is basic while BiH(3) ...

Explain why `NH_(3)` is basic while `BiH_(3)` is only feebly basic ?

Text Solution

Verified by Experts

`NH_(3)` is distinctly basic while `BiH_(3)` is feebly basic.
Nitrogen has a small size due to which the lone pair of electrons is concentrated in a small region. This means that the charge density per unit volume is high. On moving down a group, the size of the central atom increases and the charge gets distributed over a large area decreasing the electron density. Hence, the electron donating capacity of group 15 element hydrides decreases on moving down the group.
Promotional Banner

Topper's Solved these Questions

  • THE P-BLOCK ELEMENTS

    NCERT|Exercise EXERCISE|74 Videos
  • THE D AND F BLOCK ELEMENTS

    NCERT|Exercise Exercise|38 Videos
  • THE SOLID STATE

    NCERT|Exercise Solved Examples|3 Videos

Similar Questions

Explore conceptually related problems

Explain why is NH_(3) basic while PH_(3) is feebly basic in nature.

PH_3 is less basic than NH_3 .

Why Ce(OH)_(3) is more basic than Lu(OH)_(3) ?

Explain why bond angle of NH_(3) is greater than NF_(3) while bond angle of PH _(3) is less than that of PF _(3),

Assertion : NH_(3) is less basic than PH_(3) Reason: Nitrogen is more electronegative than phosphorus.

AICI_(3) is covalent while AIF_(3) is ionic This can be justified on the basic of .

Assertion (A) : PH_(3) is more basic than NH_(3) Reason (R) : EN of N is more than that of P