Home
Class 12
CHEMISTRY
The number of paramagentic species among...

The number of paramagentic species among the following is
`O_(2), CO, N_(2), C_(2), CsO_(2), BaO_(2), CO_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the number of paramagnetic species among the given molecules, we need to analyze each molecule for the presence of unpaired electrons. A species is considered paramagnetic if it has at least one unpaired electron. ### Step-by-Step Solution: 1. **O₂ (Oxygen)**: - Total electrons: 16 (8 from each O atom). - Molecular Orbital Configuration: - σ(1s)² σ*(1s)² σ(2s)² σ*(2s)² σ(2p_z)² (paired) π(2p_x)² π(2p_y)² (paired) π*(2p_x)¹ π*(2p_y)¹ (unpaired). - Unpaired Electrons: 2. - **Conclusion**: O₂ is paramagnetic. 2. **CO (Carbon Monoxide)**: - Total electrons: 14 (6 from C and 8 from O). - Molecular Orbital Configuration: - σ(1s)² σ*(1s)² σ(2s)² σ*(2s)² σ(2p_z)² (paired) π(2p_x)² π(2p_y)² (paired). - Unpaired Electrons: 0. - **Conclusion**: CO is diamagnetic. 3. **N₂ (Nitrogen)**: - Total electrons: 14 (7 from each N atom). - Molecular Orbital Configuration: - σ(1s)² σ*(1s)² σ(2s)² σ*(2s)² σ(2p_z)² (paired) π(2p_x)² π(2p_y)² (paired). - Unpaired Electrons: 0. - **Conclusion**: N₂ is diamagnetic. 4. **C₂ (Dicarbon)**: - Total electrons: 12 (6 from each C atom). - Molecular Orbital Configuration: - σ(1s)² σ*(1s)² σ(2s)² σ*(2s)² σ(2p_z)² (paired) π(2p_x)² π(2p_y)² (paired). - Unpaired Electrons: 0. - **Conclusion**: C₂ is diamagnetic. 5. **CsO₂ (Cesium Peroxide)**: - Total electrons: 18 (1 from Cs, 12 from O₂). - The outermost electrons from Cs are paired, and O₂ contributes 2 unpaired electrons. - Unpaired Electrons: 1 (from O₂). - **Conclusion**: CsO₂ is paramagnetic. 6. **BaO₂ (Barium Peroxide)**: - Total electrons: 20 (2 from Ba, 12 from O₂). - The outermost electrons from Ba are paired, and O₂ contributes 2 unpaired electrons. - Unpaired Electrons: 0. - **Conclusion**: BaO₂ is diamagnetic. 7. **CO₂ (Carbon Dioxide)**: - Total electrons: 16 (4 from C and 12 from O). - Molecular Orbital Configuration: - σ(1s)² σ*(1s)² σ(2s)² σ*(2s)² σ(2p_z)² (paired) π(2p_x)² π(2p_y)² (paired). - Unpaired Electrons: 0. - **Conclusion**: CO₂ is diamagnetic. ### Summary of Findings: - Paramagnetic Species: O₂, CsO₂ - Diamagnetic Species: CO, N₂, C₂, BaO₂, CO₂ ### Final Answer: The number of paramagnetic species among the given options is **2** (O₂ and CsO₂). ---
Promotional Banner

Topper's Solved these Questions

  • NTA JEE MOCK TEST 19

    NTA MOCK TESTS|Exercise CHEMISTRY|25 Videos
  • NTA JEE MOCK TEST 25

    NTA MOCK TESTS|Exercise CHEMISTRY|25 Videos

Similar Questions

Explore conceptually related problems

If 2s-2p mixing is not operative the diamagnetic species among the followng is/are H_(2),H_(2)^(+),Li_(2), B_(2), C_(2), N_(2), O_(2)^(-), F_(2)

The number of hypervalent species among the following CIO_(4)^(Theta),BF_(3),SO_(4)^(2-),CO_(3)^(2-) is .

The number of greenhouse gases of the following is ________. CO_(2), O_(2),N_(2)O, CH_(4), CFCs, CO, H_(2)O (g), O_(3)

How many molecules are acidic oxides among the following : CO, NO_(2), SO_(2), SO_(3), NO, N_(2)O, SiO_(2), Cl_(2)O_(7)

How many of the following are neutral CO, NO, N_(2)O, CO_(2),NO_(2), ZnO, CaO, H_(2)O

If Hund rule violate, then find the total number of species among following which whill be dimagnetic: B_(2), O_(2), N_(2)^(-), C_(2), NO, OF, N_(2)^(2-), BN

NTA MOCK TESTS-NTA JEE MOCK TEST 22-CHEMISTRY
  1. If the pK(a) of a weak and acid HA is 4.80 and the pK(b) of a weak bas...

    Text Solution

    |

  2. 500 g impure sample of CaCO(3) on heating gives 70 g of CaO. Percentag...

    Text Solution

    |

  3. Number of photons having wavelength 632.8 nm, emitted by 5 mW laser so...

    Text Solution

    |

  4. Which of the following increases in magnitude as the atomic number of ...

    Text Solution

    |

  5. The following reaction descomposes N(2)O(5)rarr 2NO(2)+(1)/(2)O(2). At...

    Text Solution

    |

  6. The P-T graph, as given below, was observed for a process on an ideal ...

    Text Solution

    |

  7. A metal crystallizes into two cubic systems - face centred cubic (fcc)...

    Text Solution

    |

  8. The resistance of a conductivity cell contaning 0.001M KCl solution at...

    Text Solution

    |

  9. The compound which acts as antioxidant in packed food is

    Text Solution

    |

  10. overset((i)H(2)O^(+))underset((ii)Delta)rarrA overset(H(2)NOH)underset...

    Text Solution

    |

  11. For the reaction The correct statement regarding above reaction i...

    Text Solution

    |

  12. The number of primary, secondary and tertiary carbons in the following...

    Text Solution

    |

  13. CH(3)-underset(O)underset(||)C-CH=CH-CH(3)overset(HBr)rarr find the ...

    Text Solution

    |

  14. How many resonating structures are possible for the following structur...

    Text Solution

    |

  15. After prolonged treatement of (A) by D(2)O // DO^(-), the maximum poss...

    Text Solution

    |

  16. Products In the above reaction, number of possible alkenes (products...

    Text Solution

    |

  17. The number of paramagentic species among the following is O(2), CO,...

    Text Solution

    |

  18. The relative humidity of air is 80% at 27^(@)C. If the aqueous tension...

    Text Solution

    |

  19. Graph between log((x)/(m)) vs log P is provided for adsorption of NH(3...

    Text Solution

    |

  20. Melamine is used in formation of melamine formaldehye resin. How many ...

    Text Solution

    |