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The quantum numbers of six electrons are...

The quantum numbers of six electrons are given below. Arrange them in order of increasing energies. If any of these combination(s) has/have the same energy lists:
` 1. n=4 , l=2 , m_(i) =-2, m_(s) =-1//2 `
`2. n=3 , l=2 , m_(l) =1 , m_(s) =+1//2`
3.`n=4 , l=2 ,m_(l)=-2, m_(s) =-1//2`
4. ` n=3 , l= 2, m_(i) =-1 , m_(s) = +1//2`
5. ` n=3 , l=1 , m_(l) =-1 , m_(s) = +1//2`
6. `n=4 , l= 1 , m_(l) =0 , m_(s) =+1//2`

Text Solution

Verified by Experts

from Heisenberg's uncertainty principal
` Deltax xx Deltap= h/(4pi) Rightarrow Deltap=1/(Deltap)=1/(Deltax). h/(4pi)`
where ,
`Deltax` = uncertainrty in position of the electron
` Deltap` = uncertainty in momentum of the electron
substituting the values in the expression of `Deltap`
` Deltap=1/(0.002nm)xx(6.626xx10^(-34) Js)/(4xx(.14))`
` =1/(2xx 10^(-12) m) xx (6. 626xx 10^(-34) Js)/(4xx 3.14)`
` 2.637xx 10^(-23) Jsm^(-1)`
`Deltap= 2.637xx 10^(-23) kgms^(-1) (1J =1kgms^(2) s^(-1))`
uncertainty in the momentum of the electron `=2.637xx 10^(-23) kgms^(-1)`
Actual momentum =`h/(4pi_(m)xx0.05 nm)`
`(6.626xx 10^(-34) Js)/(4xx3.14 xx 5.0 xx 10^(-11) m )`
`1.055 xx 10^(-24) kgms ^(-1)`
Since the magnitude of the actual momentum is smaller than the uncertainty, the value cannot be defined.
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The quantum numbers of six elements are given below. Arrange them in order of increasing energies. If any of these combinations has/have the same energies, list them. {:((1) n = 4 ",", l = 2",", m_l=-2",", m_s = - 1/2),((2) n = 3 ",", l = 2",", m_l=0",", m_s = + 1/2),((3) n = 4 ",", l = 1",", m_l= 0",", m_s = + 1/2),((4) n = 3 ",", l = 2",", m_l=-2",", m_s = - 1/2),((5) n = 3 ",", l = 1",", m_l=-1",", m_s = + 1/2),((6) n = 4 ",", l = 1",", m_l=0",", m_s = + 1/2):}

The quantum number of electrons are given below: Arrange then in order of increasing energies a. n= 4,l= 2,m_(1)= -2, m_(s)= -(1)/(2) b. n= 3,l= 2,m_(1) = 1, m_(s)= +(1)/(2) c. n= 4,l= 1,m_(1) = 0, m_(s)= +(1)/(2) e.n= 3,l= 2,m_(1)= -2, m_(s)= +(1)/(2) f. n= 4,l= 1,m_(1) = +1, m_(s)= +(1)/(2)

Explain , giving reason , which of the following sets of quantum number are not possible {:(a,n= 0 ,l = 0, m_(1) = 0, m_(s) = +1//2),(b,n= 1 ,l = 0, m_(1) = 0, m_(s) = -1//2),(c,n= 1 ,l = 0, m_(1) = 0, m_(s) = +1//2),(d,n= 2 ,l = 1, m_(1) = 0, m_(s) = -1//2),(e,n= 3 ,l = 3, m_(1) = -3, m_(s) = +1//2),(f,n= 3 ,l = 1, m_(1) = 0, m_(s) = +1//2):}

From the following sets of quantum numbers, state which are possible. Explain why the others are not possible. (i) n=0, l=0, m_(l)=0, m_(s)=+1//2 " " (ii) n=1, l=0, m_(l)=0, m_(s)=-1//2 (iii) n=1, l=1, m_(l)=0, m_(s)= +1//2 " " (iv) n=1, l=0, m_(l)=+1, m_(s)=+1//2 (v) n=3, l=3, m_(l)=-3, m_(s)=+1//2 " " (vi) n=3, l=1, m_(l)=0, m_(s)=+1//2

Which of the following sate of quantum numbers is not permissible for an electron in an atom? (i) n = 1,l = 1, m_(l) 0, m_(s) =+ 1//2 (ii) n = 3, l = 1, m_(1) =- 2, m_(s) =- 1//2 (iii) n =1, l = 1, m_(l) = 0, m_(s) =+ 1//2 (iv) n = 2, l = 0, m_(l) = 0, m_(s) = 1

From the following sets of quantum numbers , state which are possible ? (i) n=0,l=0,m_(l)=1,m_(s)= +1//2 (ii) n=2,l=1,m_(l)=0,m_(s) = -1//2 (iii) n=2, l=0,m_(1)=3,m_(s) = +1//2 (iv) n=3,l=1,m_(l)=0,m_(s) = +1//2

From the following sets quantum number state which are possible. Explain why the other are not permitted ? a. n = 0, l = 0, m= 0, s = + 1//2 b. n = 1, l = 0, m= 0, s = - 1//2 c. n = 1, l = 1, m= 0, s = + 1//2 d. n = 1, l = 0, m= +1, s = + 1//2 e. n = 0, l = 1, m= -1, s = - 1//2 f. n = 2, l = 2, m= 0, s = - 1//2 g. n = 2, l = 1, m= 0, s = - 1//2

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