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Ph-CH=CH=Ph underset(CCI(4))overset(CI(2...

`Ph-CH=CH=Ph underset(CCI_(4))overset(CI_(2))rarr X overset(2NaNH_(2))rarrYoverset(H_(2),Pd-CaCO_(3))rarrZ`
Identify product (Z) of the reaction.

A

B

C

D

`Ph-C-=C-Ph`

Text Solution

AI Generated Solution

The correct Answer is:
To identify the product (Z) of the given reaction sequence, let's break down the steps involved: ### Step 1: Identify the Starting Material The starting material is an alkene: Ph-CH=CH=Ph, which is a compound with two phenyl groups (Ph) attached to a conjugated diene. ### Step 2: Reaction with Chlorine (Cl2 in CCl4) The first reaction involves the addition of chlorine (Cl2) in carbon tetrachloride (CCl4). This reaction is an anti-addition across the double bond of the alkene. - **Product X**: The product of this reaction will be a dichlorinated compound: - Structure: Ph-CH(Cl)-CH(Cl)-Ph ### Step 3: Reaction with Sodium Amide (2NaNH2) Next, the product X undergoes a reaction with sodium amide (2NaNH2). In this reaction, the two chlorine atoms and the two hydrogen atoms from the adjacent carbon atoms will be eliminated, resulting in the formation of a triple bond. - **Product Y**: The product after this elimination will be: - Structure: Ph-C≡C-Ph (a phenyl-substituted alkyne) ### Step 4: Hydrogenation with Lindlar's Catalyst (H2, Pd-CaCO3) Finally, the alkyne (Product Y) is subjected to hydrogenation using Lindlar's catalyst (H2, Pd-CaCO3). This type of hydrogenation selectively converts alkynes to cis-alkenes. - **Product Z**: The product after this hydrogenation will be: - Structure: Ph-CH=CH-Ph (a cis-alkene) ### Final Answer The product (Z) of the reaction is **Ph-CH=CH-Ph**, which is a cis-stilbene. ---

To identify the product (Z) of the given reaction sequence, let's break down the steps involved: ### Step 1: Identify the Starting Material The starting material is an alkene: Ph-CH=CH=Ph, which is a compound with two phenyl groups (Ph) attached to a conjugated diene. ### Step 2: Reaction with Chlorine (Cl2 in CCl4) The first reaction involves the addition of chlorine (Cl2) in carbon tetrachloride (CCl4). This reaction is an anti-addition across the double bond of the alkene. ...
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