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Hydrocarbon A (C(7)H(12)) was treated wi...

Hydrocarbon A `(C_(7)H_(12))` was treated with `BH_(3)` .THF, `H_(2)O_(2), NaOH` To product `B(C_(7)H_(14)O_()` as only product.Reaction of B with TsCI//Pydridine follwored by KOH given followied by Zn//AcOH produces only co,pounds shown below:

What is correct structure of 'B'?

A

B

C

D

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An organic compound A (C_(7)H_(6)Cl_(2)) on treatment with NaOH solution gives another compound B (C_(7)H_(6)O) . B on oxidation gives and acid C (C_(7)H_(6)O_(2)) which on treatment with a mixture of conc. HNO_(3)" and "H_(2)SO_(4) gives a compound D (C_(7)H_(5)NO_(4)) . B on treatment with conc. NaOH gives a compound E (C_(7)H_(8)O)" and "C_(6)H_(5)COONa . Deduce the structures of [A], [B], [C], [D] and [E].

On ozonolysis, an organic compound (A) C_(6)H_(10) gives two aldehyde (B) C_(2)H_(4)O and (C ) C_(2)H_(2)O_(2) . Determine the structure of A, B and C .

Knowledge Check

  • Hydrocarbon A (C_(7)H_(12)) was treated with BH_(3).THF,H_(2)O_(2),NaoH to produce B(C_(7)H_(14)O) as only product. Reaction of B with TsC./pyridine followed by KOH gives C (isomeric with A) in addition to the olefinic products. Treatmet of C with Ozone followed by Zn/AcOH products only compound shows below. Q. What is correct structure of B?

    A
    B
    C
    D

  • Hydrocarbon A (C_(7)H_(12)) was treated with BH_(3).THF,H_(2)O_(2),NaoH to produce B(C_(7)H_(14)O) as only product. Reaction of B with TsC./pyridine followed by KOH gives C (isomeric with A) in addition to the olefinic products. Treatmet of C with Ozone followed by Zn/AcOH products only compound shows below. Q. What is correct structure of compound C?

    A
    B
    C
    D

  • Hydrocarbon A (C_(7)H_(12)) was treated with BH_(3).THF,H_(2)O_(2),NaoH to produce B(C_(7)H_(14)O) as only product. Reaction of B with TsC./pyridine followed by KOH gives C (isomeric with A) in addition to the olefinic products. Treatmet of C with Ozone followed by Zn/AcOH products only compound shows below. Q. What is the correct structure of A ?

    A
    B
    C
    D

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