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Which of the following statements is tru...

Which of the following statements is true ?

A

`CH_(3)CH_(2)S^(-)` is both a storger base and more nucleophilic than `CH_(3)CH_(2)O^(-)`

B

`CH_(3)CH_(2)S^(-)` isa dtronger base but is less nucleophilic than `CH_(3)CH_(2)O^(-)`

C

`CH_(3)CH_(2)S^(-)` is a weaker base but is more nucleophilic than `CH_(3)CH_(2)O^(-)`

D

`CH_(3)CH_(2)S^(-)` is both a weaker base and less nucleophilic than `CH_(3)CH_(2)O^(-)`

Text Solution

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The correct Answer is:
c

`EtS^(Theta)` is weak base than `EtO^(Theta)` but more `Nu^(Theta)` rhan `etO^(Theta)` due to less solvation and more polarizability of donar 's' atom.
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