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Select the correct order of C-O bond len...

Select the correct order of C-O bond length :

A

`[M(CO)_3(PF_3)]gt[M(CO)_3(PCI_3)]gt[M(CO_3)(PMe_3)]`

B

`[M(CO)_3(PF_3)]lt[M(CO)_3(PCI_3)]lt[M(CO_3)(PMe_3)]`

C

`[M(CO)_3(PF_3)]=[M(CO)_3(PCI_3)]=[M(CO_3)(PMe_3)]`

D

`[M(CO)_3(PF_3)]=[M(CO)_3(PCI_3)]lt[M(CO_3)(PMe_3)]`

Text Solution

Verified by Experts

The correct Answer is:
B
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If in the mixed carbonyl the other ligand is also pi acceptor it would compete with the ligand CO for gaining the metal d_(pi) electron charge The higher is the extent of back donation in CO , the lesser will be the stretching vibration frequency for C-O bond If PP_(3) is better pi-acceptor than CO then answer the following Select the correct order of C-O bond length in the following molecules . (I) [Mo(CO)_(3)(PF_(3))_(3)] (II) [Mo(CO)_(3)(PCI_(3))_(3)] (III) [Mo(CO)_(3)(P(Me)_(3)_(3)] (a) IgtIIgtIII (b) IIIgtIgtII (c) IIgtIIIgtI (d) IltIIltIII

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MOTION-COORDINATION COMPOUND-EXERCISE -2 (LEVEL I) OBJECTIVE PROBLEMS JEE MAIN
  1. There are four complexes of Ni. Select the complex/ es which will show...

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  2. Which of the following is/are paramagnetic ?

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  3. Select the correct order of C-O bond length :

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  4. The number of donor sites in dimethyl glyoxime, glycinato, diethylene ...

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  5. EAN of the central metal in the complexes K2[Ni(CN4)],[Cu(NH3)4]SO4 an...

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  6. Which of the following pair of complexes have the same EAN of the cent...

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  7. The complex that violates the Sidgwicks’s rule of EAN is

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  8. 50 ml of 0.2 M solution of a compound with empirical formula CoCl(3)....

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  9. The number of sigma bond and equal Pt-Cl bond length in Zeise’s salt i...

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  10. The disodium salt of ethylenediamminetetracetic acid can be used to es...

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  11. The oxidation number of Co in the complex ion

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  12. Which of the ligand can show linkage isomerism and acts as flexidentat...

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  13. Number of complex which are sp^3d^2 hybridised. (i) [Fe)NH3)6] Cl2 (...

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  14. For which pair of complexes is the order of values of Delta0 correct?

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  15. The EAN of platinum in potassium hexachloridoplatinate (IV) is (Atomic...

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  16. EAN of the central metal in the complexes K2[Ni(CN4)],[Cu(NH3)4]SO4 an...

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  17. Complexes [Co(SO(4))(NH(3))(5)]Br and [CoBr(NH(3))(5)]SO(4) can be dis...

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  18. Which of the following has conductance approximately equal to that of ...

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  19. Aqueous solution of Fe SO4 gives tests for both Fe^(2+) and SO4^(2-) b...

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  20. The species with spin only magnetic moment of sqrt(24) BM is:

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