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1 litre of oxygen effuses through a smal...

1 litre of oxygen effuses through a small hole in 60 min. and a litre of helium at the same temperature and pressure effuses through the same hole in 21.2 min. What is the atomic weight of Helium -

A

2.99

B

3.99

C

2.08

D

1.99

Text Solution

Verified by Experts

The correct Answer is:
B

`(r_(O_(2)))/( r_(He)) = ( 1000//60)/( 1000// 212) = ( 21.2)/( 60) = sqrt((M_(He))/(M_(O_(2)))) =sqrt( (M_(He))/( 32))`
Squaring both of sides `= ( ( 21.2)^(2))/( ( 60)^(2)) = ( M_(He))/( 32) `
`M_(He) = ((21.2)^(2) xx 32)/( ( 60)^(2)) = 3.99`
Since Helium is monoatomic so
Atomic weight = Molecular weight = 3.99
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