Home
Class 12
CHEMISTRY
The polymerisation of ethylene to linear...

The polymerisation of ethylene to linear polyethylene is represented by the reaction
`nCH_(2)=CH_(2)rarr(-CH_(2)-CH_(2)-)_(n)`
When `n` has a large integral value. Given theat the average enthalpies of bond dissociation for `C=C` and `C-C` at `298K`are `+590` and `+331kJ mol^(-1)` respectively, calculate the enthalpy of polymerisation per mole of ethylene at `298K`.

Text Solution

Verified by Experts

`-72 kJ mol^(-1)`
Promotional Banner

Topper's Solved these Questions

  • THERMOCHEMISTRY

    MOTION|Exercise Exercise - 4 Level-I|15 Videos
  • THERMOCHEMISTRY

    MOTION|Exercise Exercise - 4 Level-II|8 Videos
  • THERMOCHEMISTRY

    MOTION|Exercise Exercise - 2 (Level-II)|29 Videos
  • SURFACE CHEMISTRY

    MOTION|Exercise Exercise - 3 (Level-II)|12 Videos
  • THERMODYNAMICS

    MOTION|Exercise EXERCISE - 4 (LEVEL - II)|19 Videos

Similar Questions

Explore conceptually related problems

The bond energies of C=C and C-C at 298 K are 590 and 331 kJ mol^(-1) , respectively. The enthalpy of polymerisation per mole of ethaylene is

The polymerisation of propene to linear polypropene is represented by the reaction where n has intergral value, the average enthalpies of bond dissociation for (C =C) and (C -C) at 298K are +509 and +331 kJ mol^(-1) , respectively. the enthalpy of polymerisation is -360 kJ . Find the value of n .

The bond enthalpies of C-C , C=C and C=C bonds are 348, 610 and 835 kj // mole respectively at 298 K and 1 bar . Calculate enthalpy of polymerisation per mole of butyne at 298 K and 1 bar :

Enthalpy of polymerisation of ehtylene, as represented by the reaction , nCH_(2)=CH_(2)rarr(-CH_(2)-CH_(2)-) is -100 kJ per mole of ehtylene. Given bond enthalpy of C=C bond is 600 kJ mol^(-1) , enthalpy of C-C bond ( in kJ mol) will be:

280 gm of ethylene polymerises to polyethylene according to the equation. n(CH_(2) = CH_(2) rArr (CH_(2) - CH_(2))_(n) - The weight and mole of polyethylene formed will be:

When 100 g of ethylene polymerises entirely to polythene, the weight of polyethene formed as per the equation nCH_(2)=CH_(2) rarr (CH_(2)-CH_(2))n is :

MOTION-THERMOCHEMISTRY -Exercise - 3
  1. Using the bond enthalpy data given below, calculate the enthalpy chang...

    Text Solution

    |

  2. The enthalpy change for the following process at 25^(@) C and under co...

    Text Solution

    |

  3. The polymerisation of ethylene to linear polyethylene is represented b...

    Text Solution

    |

  4. From the following data : Enthalpy of formation of CH(3)CN=87.86 kJ/...

    Text Solution

    |

  5. The heat of combustion of acetylene is 312 Kcal . If heat of formatio...

    Text Solution

    |

  6. Using the bond enthalpy data given below, calculate the enthalpy of fo...

    Text Solution

    |

  7. Find bond enthalpy of S-S bond from the following data: C(2)H(5)-S-C...

    Text Solution

    |

  8. Find the enthalpy of S – S bond from the data. C(2) H(5)- S - S - ...

    Text Solution

    |

  9. Find the enthalpy of S – S bond from the data. S (g) = Delta H(f)^...

    Text Solution

    |

  10. The enthalpy of formation of ethane, ethylene and benzene from the gas...

    Text Solution

    |

  11. Calculate the heat of combustion of methyl alcohol at 298 K from the f...

    Text Solution

    |

  12. Calculate the electron gain enthalpy of fluorine atom using the follow...

    Text Solution

    |

  13. Cesium chloride is formed according to the following equation Cs (s)...

    Text Solution

    |

  14. The Born-Haber cycle for rubidium chloride (RbCl) is given below (the ...

    Text Solution

    |

  15. From the following data, C(s , graphite) + O(2) (g) to CO(2) (g) ...

    Text Solution

    |

  16. Calculate the mass of mercury which can be liberated from HgO at 25^(@...

    Text Solution

    |

  17. From the following data of DeltaH of the following reactions C (s) +...

    Text Solution

    |

  18. Although C(P) is usually assumed to be constant, for more accurate cal...

    Text Solution

    |

  19. Although C(P) is usually assumed to be constant, for more accurate cal...

    Text Solution

    |

  20. An intimate mixture of ferric oxide and aluminium is used as solid fue...

    Text Solution

    |