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When 100mL of 1.0M HCl was mixed with 10...

When `100mL` of `1.0M HCl` was mixed with `100 mL` of `1.0 M NaOH` in an insulated beaker at constant pressure, a temperature increase of `5.7^(@)C` was measured for the beaker and its contents (Expt.1). Because the enthalpy of neutralisation of a strong acid with a strong base is constant `(-57.0kJmol^(-1))` this experiment couldbe used to measure the calorimeter constant. In a second experiment (Expt.2), `100mL` of `2.0M` acetic acid `K_(a)=2.0xx10^(-5))` was mixed with `100mL` of `1.0M NaOH` (under identical conditions to Expt. 1) where a temperature rise of `5.6^(@)C` was measured.
Enthalpy of dissociation (in `kJ mol^(-1)`) of acetic acid obtained from the Expt. 2 is

A

`-2`

B

`-1`

C

`1`

D

`2`

Text Solution

Verified by Experts

The correct Answer is:
D
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When 100mL of 1.0M HCl was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at constant pressure, a temperature increase of 5.7^(@)C was measured for the beaker and its contents (Expt.1). Because the enthalpy of neutralisation of a strong acid with a strong base is constant (-57.0kJmol^(-1)) this experiment couldbe used to measure the calorimeter constant. In a second experiment (Expt.2), 100mL of 2.0M acetic acid K_(a)=2.0xx10^(-5)) was mixed with 100mL of 1.0M NaOH (under identical conditions to Expt. 1) where a temperature rise of 5.6^(@)C was measured. The pH of the solution after Expt. 2 ils

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