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0.05 g of a piece of metal in dilute aci...

`0.05 g` of a piece of metal in dilute acid gave `24.62 mL` of `H_(2)` at `27^(@)C` and `760mm` pressure. The `Ew` of metal is

A

25

B

`12.5`

C

50

D

`37.5`

Text Solution

Verified by Experts

The correct Answer is:
A

Volume of `H_(2)` at STP `= 24.62 xx (273)/(300) = 22.40 mL`
22400 mL of `H_(2)` at STP = 1 mole = 2 Equivalent of `H_(2)`
22.4 mL of `H_(2) = (2)/(22400) xx 22.4 = 0.002` equivalent of `H_(2) = 0.002` equivalent of metal
`:. ("Weight")/("Equivalent weight") = 0.02 rArr (0.05)/(0.002) = "Equivalent weight" = 25`
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