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A sample of NaClO(3) is converted by he...

A sample of `NaClO_(3)` is converted by heat to `NaCl` with a loss of `0.16g`of oxygen. The residue is dissolved in water and precipitated as `AgCl`. The mass of `AgCl` (in g) obtained will be: (Given : Molar mass of `AgCl = 143.5 g mol^(-1)`)

A

0.54

B

0.35

C

0.48

D

0.41

Text Solution

Verified by Experts

The correct Answer is:
C

Decomposition of `NaClO_(3)` is given as: `2NaClO_(3) overset(Delta)rarr underset("(Residue)")(2NaCl) + underset(0.16g)(3O_(2))`
No. of moles of `O_(2)` formed `= (0.16)/(32) = 5 xx 10^(-3), " "n_(NaCl) = (2)/(3) n_(O_(2)) = (2)/(5) xx 5 xx 10^(-3) = (1)/(300)`
`NaCl + Ag^(+) rarr AgCl + Na^(+)` , 1 mole of AgCl is precipitated from one mole of NaCl.
`:.` Mole of `AgCl = (1)/(300) " ":.` Mass of AgCl = Molar mass of `AgCl xx n_(AgCl)`
`= 143.5 xx (1)/(300) square 0.48 g`
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