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The formation of the oxide ion O((g))^(2...

The formation of the oxide ion `O_((g))^(2-)` requires first an exothermic and then an endothermic step as shown below.
`O_((g)) +e^(-) = O_((g))^(-) DeltaH^(@) =- 142 kJ mol^(-1)`
`O_((g))^(-) + e^(-) = O_((g))^(2-) DeltaH^(@) = 844 kJ mol^(-1)` This is because of :

A

`O^(-)` ion has comparatively larger size than oxygen atom

B

Oxygen has high electron affinity

C

`O^(-)` ion will tend to resist the addition of another electron

D

Oxygen is more electronegative

Text Solution

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The correct Answer is:
C

EGE is positive when an electron is added to anion (as repulsion between negative charges).
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The formation of the oxide ion O_(g)^(2-) requires first an exothermic and then an endothermic step as shown below: O_(g)+e^(-) rarr O_(g)^(-) , DeltaH=-142 kJ mol^(-1) O(g)+e rarr O_(g)^(2-) , DeltaH=844kJ mol^(-1) This is because: