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For the spinel structure (MgAl(2)O(4)), ...

For the spinel structure `(MgAl_(2)O_(4))`, the correct statement is//are

A

50% octahedral voids are occupied by ions

B

`Al^(3+)` is equally distributed in tetrahedral and octahedral voids

C

Oxide ions occupy CCP lattice

D

12.5% tetrahedral voids are occupied by ions

Text Solution

Verified by Experts

In spinel `O^(2-)` froms FCC unit cell where `Mg^(2+)` is present in tetrahedral voids and `Al^(3+)` is present in two octahedral voids. So 50% octahedral voids are occupied and 1/`8^(th)` i.e. 12.5% tetrahedral voids are occupied.
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