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A mixture of n mole of Nitrogen and 1 mo...

A mixture of n mole of Nitrogen and 1 mole of hydrogen is kept is a container at room, temperature. The ratio of r.m.s. velocities of hydrogen and nitrogen molecules is:

A

`sqrt(14)`

B

`sqrt(28)`

C

`n xx 14`

D

`n//26`

Text Solution

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The correct Answer is:
To find the ratio of the root mean square (r.m.s.) velocities of hydrogen and nitrogen molecules, we can follow these steps: ### Step 1: Understand the formula for r.m.s. velocity The formula for the root mean square velocity (v_rms) of a gas is given by: \[ v_{rms} = \sqrt{\frac{3RT}{M}} \] where: - \( R \) = universal gas constant - \( T \) = absolute temperature (in Kelvin) - \( M \) = molar mass of the gas (in kg/mol) ### Step 2: Identify the molar masses - For hydrogen (H₂), the molar mass \( M_H \) is approximately 2 g/mol, which is 0.002 kg/mol. - For nitrogen (N₂), the molar mass \( M_N \) is approximately 28 g/mol, which is 0.028 kg/mol. ### Step 3: Write the r.m.s. velocity for both gases - For hydrogen: \[ v_{rms, H_2} = \sqrt{\frac{3RT}{M_H}} = \sqrt{\frac{3RT}{0.002}} \] - For nitrogen: \[ v_{rms, N_2} = \sqrt{\frac{3RT}{M_N}} = \sqrt{\frac{3RT}{0.028}} \] ### Step 4: Calculate the ratio of r.m.s. velocities Now, we can find the ratio of the r.m.s. velocities of hydrogen to nitrogen: \[ \frac{v_{rms, H_2}}{v_{rms, N_2}} = \frac{\sqrt{\frac{3RT}{0.002}}}{\sqrt{\frac{3RT}{0.028}}} \] ### Step 5: Simplify the ratio The \( 3RT \) terms cancel out: \[ \frac{v_{rms, H_2}}{v_{rms, N_2}} = \sqrt{\frac{0.028}{0.002}} = \sqrt{14} \] ### Final Answer Thus, the ratio of the r.m.s. velocities of hydrogen to nitrogen is: \[ \frac{v_{rms, H_2}}{v_{rms, N_2}} = \sqrt{14} \]

To find the ratio of the root mean square (r.m.s.) velocities of hydrogen and nitrogen molecules, we can follow these steps: ### Step 1: Understand the formula for r.m.s. velocity The formula for the root mean square velocity (v_rms) of a gas is given by: \[ v_{rms} = \sqrt{\frac{3RT}{M}} \] ...
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