Si reacts with CH3 CI at 573 K in the pr...

Si reacts with `CH_3 CI` at 573 K in the pressure of `Cu` powder to form methyl substituted chlorosilanes. Among the given methyl substituted chlorosilanes, whose yield is minimum?

`CH_(3)SiCl_(3)`

`(CH_(3))_(2)SiCl_(2)`

`(CH_(3))_(3)SiCl`

`(CH_(3))_(4)Si`

Text Solution

Verified by Experts

The correct Answer is:

The approx yield of various methyl substituted chlorosilanes is as follows :
`CH_(3)SiCl_(3) lt 10-30^(%)` yield
`(CH_(3))_(2)SiCl_(2)lt 50%` yield
`(CH_(3))_(3)SiCl lt 10%` yield
`(CH_(3))_(4)Si lt 5%` yield
Thus, yield of `(CH_(3))_(4)` Si is minimum.

Topper's Solved these Questions

TS EAMCET 2017
TS EAMCET PREVIOUS YEAR PAPERS|Exercise CHEMISTRY|40 Videos
TS EAMCET 2018 (7 MAY SHIFT 1)
TS EAMCET PREVIOUS YEAR PAPERS|Exercise CHEMISTRY|40 Videos

Similar Questions

Explore conceptually related problems

In the addition of HBr to 1, 3-buta diene, one product is called the kinetic product and the other is called the thermodynamic product. Which of the following description applies to kinetic product? a) 1, 2 product b) 1, 4 product c) most stable d) least stable e) formed slowest f) formed fastest g) formed at low pressure h) formed at high temperature i) most substituted alkene j) least substituted alkene k) bromide attack at most substituted site l) bromide attack at least substituted site

Hydrolysis of methyl acetate in aqueous solution has been studied by titrating the liberated acetic acid against sodium hydroxide. The concentration of the ester at different times is given below. Show that it follows a pseudo first order reaction, as the concentration of water remains nearly constant (55 mol L^(-1)), during the course of the reaction. What is the value of k in this equation? Rate =k'[CH_(3) COOCH_(3) ][H_(2)O]

Hydrogen bonding is said to be formed, -when sightly acidic hydrogen-atom attached to a strongly, electronegative fluorine, oxygen or nitrogen atom. is held with weak. electrostatic forces by the non-bonded pair of electrons of another atom. The co-ordination number of hydrogen in such cases is two. It acts as a bridge between two atoms, to one of which it is covalently bonded and to other attached through electrostatic forces, also called hydrogen bond. Though the hydrogen atoms in a methyl group are not polarised, if an electronegative group like chloro, carbonyl, nitro or cyano (in order to increase electronegativity) is attached to it, the C-H bond gets polarised due to the inductive effect and the hydrogen atom becomes slightly acidic resulting in the formation of weak hydrogen bonds. Though a weak bond the H-bond effects is large number of the physical properties of compounds some of which are - Boiling points of liquids - Solubility of polar compounds in polar solvents (containig H attached with strong electronegative atom) - Viscosity of liquids . Acidity Which of the following combinations can involve hydrogen bonding I) Mixture of KF and HF " " II) Mixture of CH_(3)COCH_(3) and CHCI_(3) III) Mixture of NH_(4) CI and H_(2)O" " IV) Mixture of CH_(3) and H_(2)O

A hydrocarbon (X) with vapour density = 27 containing C = 88.88% decolourizes KMnO_(4) and Br_(2) water without evolving HBr. It gave no ppt. with ethereal ammonical AgNO_(3) or Cu_(2)CI_(2) When reacted with dil. H_(2)SO_(4) in the presence of mercuric sulphate, methyl ethyl ketone (Y) is formed. The compound is

The Vapour pressure of ethyl alcohol and methyl alcohol are 45 mm and 90mm . An ideal solution is formed at the same temperature by mixing 46g of C_(6)H_(5)OH with 40g of CH_(3)OH . Total vapour pressure of the solution approximaately x cm .x is __________________

TS EAMCET PREVIOUS YEAR PAPERS-TS EAMCET 2018 (4 MAY SHIFT 1)-Chemistry

When sodium (Na) metal is dissolved in liquid ammonia ("NH"(3)), it im...
Text Solution
|
Identify the correct statements from the following (a) In orthobor...
Text Solution
|
Si reacts with CH3 CI at 573 K in the pressure of Cu powder to form me...
Text Solution
|
When vegetation is brunt in the absence of oxygen, which of the follow...
Text Solution
|
IUPAC name for the following compound is CH3 -overset(overset(CI)|) ...
Text Solution
|
What are the products formed in the reaction given below? Ph-CH2 - C...
Text Solution
|
The major product obtained in the reaction of isobutyl benzene with ac...
Text Solution
|
A compound is formed by elements of X, Y and Z . Atoms of Z (anions) f...
Text Solution
|
A litre of sea water (which weighs 1030 g) contains 6xx10^(-3) g of d...
Text Solution
|
At 300 K, a one litre solution of sucrose (molecular weight : 342 ) wa...
Text Solution
|
The EMF of a galvanic cell consisting of two hydrogen electrodes is 0....
Text Solution
|
If the rate constants of a reaction at 500K and 700K are 0.002 s^(-1) ...
Text Solution
|
The following graph is obtained for physisorption of a gas as a functi...
Text Solution
|
Identify the correct set of suphide ores from the following
Text Solution
|
Identify the reactions in which N2 is liberated (a) (NH4) 2 SO4 + Na...
Text Solution
|
What are X and Y, respectively in the following reactions? Au + "aqu...
Text Solution
|
Which of the following sets correctly represents the increasing parama...
Text Solution
|
Which of the following molecules / ions can exhibit isomerism? (A) T...
Text Solution
|
The formation of terylane ( or decron) from ethylene glycol and tereph...
Text Solution
|
Which of the following carbohydrates has a glycosidic linkage?
Text Solution
|