Home
Class 12
CHEMISTRY
The compressibility factor (Z) of a gas ...

The compressibility factor (Z) of a gas at critical state is
`(T_(e)=(8a)/(27Rb),p_(e)=(a)/(27b^(2)),V_(e)=3b)`

A

`(8)/(3)`

B

1

C

`(3)/(8)`

D

0.5

Text Solution

Verified by Experts

The correct Answer is:
C

Given , ` T_(c) = (8a)/(27 Rb)` ,
` p_(c) = (a)/(27b^(2)), V_(c) = 3b `
`because `Compressibility factor ` (Z) = (pV)/(RT) `
`(Z) = [(a)/(27b^(2))] xx [3b] xx[(R.27b)/(R.8a)]`
`Z = 3/8`
Hence, option (C) is the correct answer .
Promotional Banner

Topper's Solved these Questions

  • TS EAMCET 2019 (4 MAY SHIFT 2)

    TS EAMCET PREVIOUS YEAR PAPERS|Exercise CHEMISTRY|40 Videos

Similar Questions

Explore conceptually related problems

The essential conditions for liquefaction of gases were discovered by Andrews in 1869 as a result of his study of pressure-volume-temperature relationship for CO_(2) . It was found that above a certain temperature, it was impossible to liquefy a gas whatever the pressure was applied. The temperature below which the gas can be liquefied by the application of pressure alone is called critical temperature (Tc). The pressure required to liquefy a gas at this temperature is called the critical pressure (Pc). The volume occupied by one mole of the substance at the critical temperature and pressure is called critical volume. Critical constants are related with van der waals' constant as follows: V_( c) = 3b, P_( c) =a/(27b^(2)), T_( c) =(8a)/(27 Rb) The values of critical volumes of four gases A, B, C and D are 0.025L, 0.312L, 0.245L and 0.432L respectively. The gas with larger molecular diameter will be :

Critical constants are related with van der waals' constant as follows: V_( c) = 3b, P_( c) =a/(27b^(2)), T_( c) =(8a)/(27 Rb) The pressure required to liquefy a gas at the critical temperature is called :

Two springs of force constants 300 N/m (springs A) and 400 N/m (spring B) are joined together in series. The combination is compressed by 8.75 cm. The ratio of energy stored in A and B is (E_(A))/(E_(B)) . The (E_(A))/(E_(B)) is equal to

At a particular temperature and pressure for a real gas Van der Waal's equation can be written as: (P + a/(V^(2)m)) (V_(m) -b) =RT where Vm is molar volume of gas. This is cubic equation in the variable Vm and therefore for any single value of P & T there should be 3 values of Vm. Which are shown in graph as Q, M and L. As temperature is made to increase at a certain higher temperature the three values of Vm becomes identical. The temperature, pressure & molar volume at point X are called Tc, Pc & Vc for real gas. The compressibility factor in terms of Pc, Vc and T is called Zc. The value of critical compressibility factor Zc is approximately

Relationship between P, V and E for a gas is

TS EAMCET PREVIOUS YEAR PAPERS-TS EAMCET 2019 (6 MAY SHIFT 1)-CHEMISTRY
  1. Match the following : The correct answer is

    Text Solution

    |

  2. Which of the following is/are correct for Boyle's law ?

    Text Solution

    |

  3. The compressibility factor (Z) of a gas at critical state is (T(e)=(...

    Text Solution

    |

  4. The number of moles of H(2) which is required to produce 10 moles of N...

    Text Solution

    |

  5. Match the following : The correct answer is

    Text Solution

    |

  6. What is the standard enthalpy of rection (in kJ) when two moles of Fe(...

    Text Solution

    |

  7. In which of the following plots, an endothermic reaction if correctly ...

    Text Solution

    |

  8. What is the order of relative basic strength of ClO(2)^(-),ClO(3)^(-),...

    Text Solution

    |

  9. How many water molecules present in CuSO(4).5H(2)O are hydrogen bonded...

    Text Solution

    |

  10. Which gas/gases evolve (s) when sodium metal is reacted with at room t...

    Text Solution

    |

  11. A and B are formed when borax, is dissolved in water. C and B are form...

    Text Solution

    |

  12. How many nearest neighbours are there for Si and O atoms in quartz cry...

    Text Solution

    |

  13. Match the following : The correct answer is

    Text Solution

    |

  14. Which of the following method is adopted to obtain gasoline from crude...

    Text Solution

    |

  15. Which of the following statements is correct in the Kolbe's electrolys...

    Text Solution

    |

  16. The correct order of rates of C-Br bond ionisation of the following br...

    Text Solution

    |

  17. If an element having atomic number 96 crystallises in cubic lattice wi...

    Text Solution

    |

  18. The vapour pressure of pure C""Cl(4) (molar mass =154gmol^(-1)) and Sn...

    Text Solution

    |

  19. A camphor sample melts at 176^(@)C.K(f) for camphor is 40 K kg mol^(-1...

    Text Solution

    |

  20. If 'A' is the reactant and 'P' is the product, which one of the follow...

    Text Solution

    |