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The concentration of an organic compound...

The concentration of an organic compound in chloroform is 6,15 g per 100 mL of solution. A portion of this solution in a 5 cm polarimeter tube causes an observed rotation of -`1.2^(@)`. What is the specific rotation of the compound?

A

`+12^(@)`

B

` -3.9^(@)`

C

`-39^(@)`

D

`+61.5^(@)`

Text Solution

Verified by Experts

The correct Answer is:
C

C=6.15g
`[alpha]_("observed")`=-`1.2^(@)`
=l=5cm
therfore specific rotation of compound,
`[alpha]=([alpha]_(observed))/(lxxC)=(-1.2)/(5xx6.15/1000)=-39^(@)`
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