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138 g of ethyl alcohol is mixed with 72 ...

138 g of ethyl alcohol is mixed with 72 g of water. The ratio of mole fraction of alcohol to water is

A

`3:4`

B

`1:2`

C

`1:4`

D

`1:1`

Text Solution

Verified by Experts

The correct Answer is:
(a)

Weight of ethyl alcohol = 138g
Weight of water = 72 g
No. of moles = `(Weight)/("Molecular weight")`
Number of moles of ethyl alcohol` ((1)) = [n_(1)= (138)/(46)=3]`
Number of moles of water `(H_(2)O) (n_(2)) =[ n_(2)=(72)/(18)=4]`
Mole fraction of `C_(2)H_(5)OH (x_(1)) = (n_(1))/(n_(1))+(n_(2)) = (3)/(3+4)=(3)/(7)`
Mole fraction of` H_(2)O (x_(2))` = `(n_(2))/(n_(1)+n_(2)) = (4)/(3+4) = (4)/(7)`
there Ratio of mole fractions `((x_(1))/(x_(3)))= (3/7)/(4/7)=(3)/(4)`
`therefore x_(1): x_(2)= 3:4`
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