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The rate constant of a first order react...

The rate constant of a first order reaction at `27^@C` is `10^(-3)mi n^(-1)`. The temperature coefficient of this reaction is 2. What is the rate constant (in mi`n^(-1)`) at `17^@C` for this reaction?

A

`10^(-3)`

B

`5xx10^(-4)`

C

`2xx10^(-3)`

D

`2xx10^(-3)`

Text Solution

Verified by Experts

The correct Answer is:
B

Temperature coefficient `= (k+10)/k`
`implies (K_(1^@ C) +10^@C)/K_(17^@C)=2`
`implies K_(17^@C)= 10^(-3)/2`
`= 5 xx 10^(-4) mi n^(-1)`
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