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Ethanol, when reacted with PCI(5) gave ...

Ethanol, when reacted with `PCI_(5)` gave A,`PCI_(3) and HC`I. A reacts with silver nitrite to from B (major product) and AgCI. A and B are respectively.

A

`C_(2)H_(5)CI` and `C_(2)H_(5)OC_(2)H_(5)`

B

`C_(2)H_(6)` and `C_(2)H_(5)OC_(2)H_(5)`

C

`C_(2)H_(5)CI` and `C_(2)H_(5)NO_(2)`

D

`C_(2)H_(6)` and `C_(2)H_(5)NO(2)`

Text Solution

Verified by Experts

The correct Answer is:
c
`C_(2)H_(5)OH+PCI_(5)tounderset((A))(C_(2)H_(5))Cl+POCl_(3)+HCl`
`underset((A))(C_(2)H_(5))Cl+AgNO_(2)tounderset((B))(C_(2)H_(5))NO_(2)+AgCl`
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SIA PUBLICATION-ORGANIC CHEMISTRY-II-MCQ
  1. Which one of the following is a secondary alcohol?

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  2. Which one of the following pairs of compounds are functional isomers?

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  3. Ethanol, when reacted with PCI(5) gave A,PCI(3) and HCI. A reacts wit...

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  4. Chloraethane reacts with X to from diethyl ether. What is X?

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  5. 3 moles of ethanol react with one mole of phosphorus tribromide to for...

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  6. Absolute alcohol (100%alcohol) is prepared by distilling reactified sp...

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  7. Which of the following is Lucas reagent?

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  8. Which of the following is a tertiary alcohol?

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  9. Absolute alcohol is prepared by distillation of rectified spirit in th...

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  10. Ethyne is treated with 30% H(2)SO(4) in the presence of 1% mercuric su...

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  11. Which one of the following reactions does not yield an alkyl halide?

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  12. The alcohol that produces turbidity immediately with ZnCl(2)//conc. HC...

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  13. An isomer of ethanol is

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  14. When an alkyl halide reacts with an alkoxide, the product is

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  15. Compound A reacts with PCl(5) to give B which on treatment with KCN fo...

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  16. Diethylether is prepared by passing ethyl alcohol vapours over a catal...

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  17. Alcohol manufactured from water gas is

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  18. Old bottles of ether are dangerous because they frequently contain hig...

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  19. The IUPAC name of is

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  20. Ethyl alcohol when passed over copper at 300^(@)C is dehydrogenated to...

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