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What is the correction tems in the pre...

What is the correction tems in the pressure for real gas in comparison to the ideal gas ?

A

`n^2/V^2`

B

`(aV^2)/n^2`

C

`(an^2)/V^2`

D

`(an^2)/V-nb`

Text Solution

Verified by Experts

The correct Answer is:
C

According to ideal gas equation ,
PV=nRT
Since, `P_"observed" lt P_"ideal"`, a correction term is added to observed pressure which are introduced by vander waal.
Ideal pressure `P_i` = Observed pressure or real pressure + Correction term
`P_i=P_r+p`
Since , `p alpha (n/V)^2`
`p=(an^2)/V^2`
a-Vander waal constant
n-number of moles of real gas
V-Volume of the gas
`rArr P_i=P_r + (an^2)/v^2`
Ideal gas equation is modified as ,
`therefore` Correction term in pressure for real gas is `(an^2)/V^2`
`(P+(an^2)/v^2) (V-nb) = nRT`
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