Home
Class 12
CHEMISTRY
There is not certainty that the reaction...

There is not certainty that the reaction will be spontaneous even if `DeltaH` is negative-explain it, state its limitation and exception.

Promotional Banner

Topper's Solved these Questions

  • CHEMICAL THERMODYNAMICS

    CHHAYA PUBLICATION|Exercise Numerical Problems|47 Videos
  • CHEMICAL THERMODYNAMICS

    CHHAYA PUBLICATION|Exercise Practice Set 6|15 Videos
  • CHEMICAL THERMODYNAMICS

    CHHAYA PUBLICATION|Exercise SHORT TYPE QUESTIONS|37 Videos
  • CHEMICAL KINETICS

    CHHAYA PUBLICATION|Exercise EXERCISE (NUMERICAL PROBLEMS)|37 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    CHHAYA PUBLICATION|Exercise PRACTICE SET 15|15 Videos

Similar Questions

Explore conceptually related problems

State one limitation of Wartz reaction.

If the value of DeltaH and DeltaS are of following type, then at what condition a reaction will occur spontaneously? (i) DeltaH gt0 and DeltaSgt0 (ii) DeltaH lt0 and DeltaS gt0

Under which of the following conditions a reaction will occur spontaneously? (i) DeltaH lt0 and DeltaS lt0 (ii) DeltaH gt0 and DeltaS lt0 .

Explain: in a chemical reaction if (i) DeltaH lt 0 and DeltaS gt0 , the spontaneity of the reaction is independent of temperature. (ii) DeltaH gt0 and DeltaS gt0 , the spontaneity of the reaction is dependent of temperature.

Write the classical definition of probability and state its limitations.

For the reaction, 2A+B to C,DeltaH=400kJ*mol^(-1) & DeltaS=0.2kJ*K^(-1)*mol^(-1) at 298K. At what temperature will the reaction become spontaneous considering DeltaH,DeltaS to be constant over the temperature range?

For the following reaction at 298K 2X + Y rarr Z DeltaH = 300 kj mol (-1) and DeltaS = 0.2 kj K^(-1) mol^(-1) At what tempreature will the reaction become spontaneous considering Delta H and DeltaS to be constnt over the temperature range?

(i) State hess's law. (ii) For the following reaction at 298K 2X+Y to Z DeltaH=300kJ*mol^(-1) and DeltaS=0.2kJ*K^(-1)*mol^(-1) At what temperature will the reaction become spontaneous considering DeltaH and DeltaS to be constant over the temperature range?

Values of Delta H Delta S for the given reaction are -95.4 kJ and -198.3 J*K^(-1) respectively: N_(2)(g)+3H_(2)(g) to 2NH_(3)(g) State whether the reaction will be spontaneous at 500 K or not. Consider Delta H and DeltaS are independent of temperature.

CHHAYA PUBLICATION-CHEMICAL THERMODYNAMICS-LONG TYPE QUESTIONS
  1. (i) What is the difference betweenn the enthalpy of formation and the ...

    Text Solution

    |

  2. What do you mean by heat of reaction or enthalpy of reaction? What are...

    Text Solution

    |

  3. (i) What do you mean by heat of reaction at constannt volume and heat ...

    Text Solution

    |

  4. (i) Show that heat of reaction at constant volume is equal to the chan...

    Text Solution

    |

  5. (i) State annd explain with example the Hess's law of constant heat su...

    Text Solution

    |

  6. Define: (i) Heat of combustion, (ii) Heat of formation, (iii) Heat of ...

    Text Solution

    |

  7. Give reason for the necessity of second law of thermodynamics.

    Text Solution

    |

  8. Write down the Clausius and Planck-Kelvin statement of the second law ...

    Text Solution

    |

  9. Define entropy from molecular point of view. At a particular temperatu...

    Text Solution

    |

  10. What do you mean by entropy of fusion and entropy of vaporisation? Giv...

    Text Solution

    |

  11. What is the physical significance of entropy ? Write the second law of...

    Text Solution

    |

  12. Show that in a process at constant temperature and pressure, the Gibbs...

    Text Solution

    |

  13. (i) What is the relation between Gibbs free energy change and spontane...

    Text Solution

    |

  14. If the value of DeltaH and DeltaS are of following type, then at what ...

    Text Solution

    |

  15. Under which of the following conditions a reaction will occur spontane...

    Text Solution

    |

  16. How does the spontaneity of an endothermic reaction depend on temperat...

    Text Solution

    |

  17. How does the spontaneity of an exothermic reaction depend on temperatu...

    Text Solution

    |

  18. There is not certainty that the reaction will be spontaneous even if D...

    Text Solution

    |

  19. Give the mathematical definition of entropy change. Discuss the relati...

    Text Solution

    |

  20. (i) Spontaneity of a process can be determined from the entropy change...

    Text Solution

    |