Home
Class 12
CHEMISTRY
In some reactions thallium resembles alu...

In some reactions thallium resembles aluminium, whereas in others it resembles with group - I metals. Support this statement by giving some evidences.

Text Solution

Verified by Experts

Both thallium and aluminium belong to group - 13 and thus have a general electronic configuration of `ns^2 np^1`. Both Al and Tl exhibit + 3 oxidation statems and form compounds like `AlCl_3 and TlCl_3` respectively. Both of them form octahedral ions like `[AlF_6]^(3-) and [TlF_6]^(3-)`. Again, due to inert pair effect, Tl shows oxidation state like the alkali metals of group -1 and forms `TlCl, Tl_2O, TlClO_4`, etc. TlOH like alkali metal hydraxides, dissolve in water to form solutions that are stronglyallkaline in nature. Again, `Tl_2CO_3` is water soluble and `Tl_2SO_4` forms alum like that of the alkali metals.
Promotional Banner

Topper's Solved these Questions

  • SOME p-BLOCK ELEMENTS

    CHHAYA PUBLICATION|Exercise HIGHER ORDER THINKING SKILL (HOTS) QUESTIONS|26 Videos
  • SOME p-BLOCK ELEMENTS

    CHHAYA PUBLICATION|Exercise ENTRANCE (QUESTION BANK)|34 Videos
  • SOME p-BLOCK ELEMENTS

    CHHAYA PUBLICATION|Exercise SOLVED WBCHSE SCANNER|35 Videos
  • SOLID STATE

    CHHAYA PUBLICATION|Exercise PRACTICE SET 1|13 Videos
  • SURFACE CHEMISTRY

    CHHAYA PUBLICATION|Exercise Practice set 5|13 Videos

Similar Questions

Explore conceptually related problems

Explain why beryllium resembles with aluminium, placed diagonally to each other.

Mention some characteristics in which nitrogen differs form the other members of the group .

The chemistry of the actinoid elements is not so smooth as that of the lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements.

Although lithium and magnesium resemble each other in properties due to diagonal relationship, the following statement which is not correct is-

Give reason ammonia is soluble in water whereas other group 15 hydrides are insoluble.

Some organisms resemble other organisms and thus escape from enemies. This phenomenon is known as :

A group of related genera which resemble each other in floral characteristics represent

Beryllium & magnesium do not give colour to flame whereas other alkaline earth metals do so. Why?

The periodicity is related to the electronic configuration that is all chemical and physical properties are a manifestation of the electronic configuration of the elements.the atomic and ionic radii genreally decrease in a period from left to right as a consequence the ionization enthalpies genrally increase and electron gain enthalpies become more negative across a period in other words the ionization enthalpy of the extreme left element element in a period is the least and the electron gain enthalpy of the element on the extreme right is the highest negative.this results into highly chemical reactivity at the two extremes and the lowest in the centre similarly down the group the increase in atomic and ionic radii result in gradual decrease in ionization enthalpies and a regular decrease (with exception in some third period elements)in electron gain enthalpies in the csea of main group elements. reducing and oxidizing behaviour of the elements metallic and non metallic character of elements acidic,basic,amphoteric and neutral charcter of the oxides of the elements The correct order of the metallic character is