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Amongst the following, the one which can...

Amongst the following, the one which can exist in free state as a stable compound is-

A

`C_(7)H_(9)O`

B

`C_(8)H_(12)O`

C

`C_(6)H_(11)O`

D

`C_(10)H_(17)O_(2)`

Text Solution

Verified by Experts

The correct Answer is:
B

Double Bond Equivalent of a compound is given by, `DEB = (sum(v-2))/(2)+1`, where n = number of atoms of a particular type present in the molecule, v = valency of each atom present in the molecule.
DEB values for the given compounds area as follow:
`C_(7)H_(9)O:(7(4-2)+9(1-2)+1(2-2))/(2)+3.5`
`C_(8)H_(12)O:(8(4-2)+12(1-2)+1(2-2))/(2)+1=3`
`C_(10)H_(17)O_(2):(10(4-2)+17(1-2)+2(2-2))/(2)+1=2.5`
Compound with fractional DEB values are unstable in free state.
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