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Which out of CH(3)CH(2)overset(* *)(N)H(...

Which out of `CH_(3)CH_(2)overset(* *)(N)H_(2)andCH_(3)COoverset(* *)(N)H_(2)` is more basic and why?

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Which one between the two CH_(3)COoverset(Theta)(C)H_(2) and CH_(3)COoverset(Theta)(C)HOCH_(3) is more stable and why?

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