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The conjugated dienes are more reactive ...

The conjugated dienes are more reactive than alkenes which in turn are more reactive than alkynes towards electrophilic addition reactions- explain.

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The reactivity of alkenes, alkynes or conjugated dienes towards electrophilic addition reaction depends on the stability of the intermediate carbocation obtained in the rate-determining step by addition of the electrophile `(E^(+))`

Out of the three carbocations (Ia, IIa and IIIa) is the most stable because it is stabilised by resonance. Again, out of (Ia) and (IIa), (IIa) is less stable because the positive charge in it is placed on a more electronegative `sp^(2)`-hybridised carbon atom. Thus, the stabilities of these carbocations follow the order: `IIIa gt Ia gt IIa`. Therefore, the order of reactivity of these compounds is: conjugated diene `gt` alkene `gt` alkyne
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CHHAYA PUBLICATION-HYDROCARBONS-HIGHER ORDER THINKING SKILL (HOTS) QUESTIONS
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  2. Which alkenes are formed on dehydrating the following alcohols in pres...

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  3. The conjugated dienes are more reactive than alkenes which in turn are...

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  4. Calculate the resonance energy of 1,3-butadiene from the following dat...

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  11. Which ring (A to B) in each of the following compounds will undergo ni...

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  13. Which ring (A to B) in each of the following compounds will undergo ni...

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  14. Write the names and structures of the compounds formed during Friede...

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  15. Write the names and structures of the compounds formed during Friede...

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  16. Write the names and structures of the compounds formed during Friede...

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  17. Show the formation of the electrophile in each case: Cl2//AlCl3

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  18. Show the formation of the electrophile in each case: Br2//Fe

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  19. Show the formation of the electrophile in each case: conc.HNO3+conc....

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