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Which one is the correct order of acidi...

Which one is the correct order of acidity-

A

`HC-=CHgtCH_3-C-=CHgtCH_2=CH_2gtCH_3-CH_3`

B

`HC-=CHgtCH_2=CH_2gtCH_3-C-=CHgtCH_3-CH_3`

C

`CH_3-CH_3gtCH_2=CH_2gtCH_3-C-=CHgtHC-=CH`

D

`CH_2=CH_2gtCH_3CH=CH_2gtCH_3-CH_3gtHC-=CH`

Text Solution

Verified by Experts

For a C-atom in hybridised state, acidic character increases with increase of the s-character. Again the presence of alkyl group reduces the acidic property due to its `+I` effects. Hence the order of acidity of the give compounds:
`HC-= overset(sp)(C)H gt CH_(3) - C-= overset(sp)(C)H gt CH_(2) = overset(sp^(2))(C)H_(3) - overset(sp^(3))(C)H_(3)`
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